N‑Heterocycle-Ligated Borocations as Highly Tunable Carbon Lewis Acids

The relative (to BEt3) hydride ion affinity (HIA) of a series of acridine borenium salts has been calculated, with some HIAs found to be similar to that for [Ph3C]+. The HIA at the acridine C9 position is controlled by both acridine and the boron substituents, the latter presumably affecting the str...

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Veröffentlicht in:	Organometallics 2017-12, Vol.36 (24), p.4952-4960
Hauptverfasser:	Radcliffe, James E, Dunsford, Jay J, Cid, Jessica, Fasano, Valerio, Ingleson, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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