A gel aging effect in the synthesis of open-framework gallium phosphates: structure solution and solid-state NMR of a large-pore, open-framework material† †Electronic supplementary information (ESI) available. CCDC 1577782 and 1577783. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7dt03709k

History of gel precursors affects the resulting product in gallium phosphate crystallisation allowing isolation of a 14-ring channel structure. The templated zeolite-analogue GaPO-34 (CHA structure type) crystallises from a gel precursor Ga 2 O 3  : 2H 3 PO 4  : 1HF : 1.7SDA : 70H 2 O (where SDA = s...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry 2017-11, Vol.46 (48), p.16895-16904
Hauptverfasser: Broom, Lucy K., Clarkson, Guy J., Guillou, Nathalie, Hooper, Joseph E., Dawson, Daniel M., Tang, Chiu C., Ashbrook, Sharon E., Walton, Richard I.
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Sprache:eng
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