Enhanced effect of HAH on citric acid-chelated Fe(II)-catalyzed percarbonate for trichloroethene degradation
This work demonstrates the impact of hydroxylamine hydrochloride (HAH) addition on enhancing the degradation of trichloroethene (TCE) by the citric acid (CA)-chelated Fe(II)-catalyzed percarbonate (SPC) system. The results of a series of batch-reactor experiments show that TCE removal with HAH addit...
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| Veröffentlicht in: | Environmental science and pollution research international 2017-11, Vol.24 (31), p.24318-24326 |
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| creator | Fu, Xiaori Brusseau, Mark L. Zang, Xueke Lu, Shuguang Zhang, Xiang Farooq, Usman Qiu, Zhaofu Sui, Qian |
| description | This work demonstrates the impact of hydroxylamine hydrochloride (HAH) addition on enhancing the degradation of trichloroethene (TCE) by the citric acid (CA)-chelated Fe(II)-catalyzed percarbonate (SPC) system. The results of a series of batch-reactor experiments show that TCE removal with HAH addition was increased from approximately 57 to 79% for a CA concentration of 0.1 mM and from 89 to 99.6% for a 0.5 mM concentration. Free-radical probe tests elucidated the existence of hydroxyl radical (HO
•
) and superoxide anion radical (O
2
•-
) in both CA/Fe(II)/SPC and HAH/CA/Fe(II)/SPC systems. However, higher removal rates of radical probe compounds were observed in the HAH/CA/Fe(II)/SPC system, indicating that HAH addition enhanced the generation of both free radicals. In addition, increased contribution of O
2
•-
in the HAH/CA/Fe(II)/SPC system compared to the CA/Fe(II)/SPC system was verified by free-radical scavengers tests. Complete TCE dechlorination was confirmed based on the total mass balance of the released Cl
−
species. Lower concentrations of formic acid were produced in the later stages of the reaction for the HAH/CA/Fe(II)/SPC system, suggesting that HAH addition favors complete TCE mineralization. Studies of the impact of selected groundwater matrix constituents indicate that TCE removal in the HAH/CA/Fe(II)/SPC system is slightly affected by initial solution pH, with higher removal rates under acidic and near neutral conditions. Although HCO
3
−
was observed to have an adverse impact on TCE removal for the HAH/CA/Fe(II)/SPC system, the addition of HAH reduced its inhibitory effect compared to the CA/Fe(II)/SPC system. Finally, TCE removal in actual groundwater was much significant with the addition of HAH to the CA/Fe(II)/SPC system. The study results indicate that HAH amendment has potential to enhance effective remediation of TCE-contaminated groundwater. |
| doi_str_mv | 10.1007/s11356-017-0070-7 |
| format | Article |
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•
) and superoxide anion radical (O
2
•-
) in both CA/Fe(II)/SPC and HAH/CA/Fe(II)/SPC systems. However, higher removal rates of radical probe compounds were observed in the HAH/CA/Fe(II)/SPC system, indicating that HAH addition enhanced the generation of both free radicals. In addition, increased contribution of O
2
•-
in the HAH/CA/Fe(II)/SPC system compared to the CA/Fe(II)/SPC system was verified by free-radical scavengers tests. Complete TCE dechlorination was confirmed based on the total mass balance of the released Cl
−
species. Lower concentrations of formic acid were produced in the later stages of the reaction for the HAH/CA/Fe(II)/SPC system, suggesting that HAH addition favors complete TCE mineralization. Studies of the impact of selected groundwater matrix constituents indicate that TCE removal in the HAH/CA/Fe(II)/SPC system is slightly affected by initial solution pH, with higher removal rates under acidic and near neutral conditions. Although HCO
3
−
was observed to have an adverse impact on TCE removal for the HAH/CA/Fe(II)/SPC system, the addition of HAH reduced its inhibitory effect compared to the CA/Fe(II)/SPC system. Finally, TCE removal in actual groundwater was much significant with the addition of HAH to the CA/Fe(II)/SPC system. The study results indicate that HAH amendment has potential to enhance effective remediation of TCE-contaminated groundwater.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-017-0070-7</identifier><identifier>PMID: 28889360</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Carbonates - chemistry ; Chelating Agents - chemistry ; Citric acid ; Citric Acid - chemistry ; Dechlorination ; Degradation ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental Restoration and Remediation - methods ; Environmental science ; Ferrous Compounds - chemistry ; Formic acid ; Free radicals ; Groundwater ; Groundwater - analysis ; Groundwater pollution ; Hydroxyl radicals ; Hydroxylamine ; Hydroxylamine - chemistry ; Iron ; Mineralization ; pH effects ; Research Article ; Superoxide ; Trichloroethylene ; Trichloroethylene - chemistry ; Waste Water Technology ; Water Management ; Water Pollutants, Chemical - chemistry ; Water Pollution Control ; Water Pollution, Chemical - prevention & control</subject><ispartof>Environmental science and pollution research international, 2017-11, Vol.24 (31), p.24318-24326</ispartof><rights>Springer-Verlag GmbH Germany 2017</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c507t-f2a96e2a99a9e2d1120de09883c34ddff41c4e0d67a122fe09c7f1a1ce4dc66d3</citedby><cites>FETCH-LOGICAL-c507t-f2a96e2a99a9e2d1120de09883c34ddff41c4e0d67a122fe09c7f1a1ce4dc66d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11356-017-0070-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11356-017-0070-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>230,314,780,784,885,27924,27925,41488,42557,51319</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28889360$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Fu, Xiaori</creatorcontrib><creatorcontrib>Brusseau, Mark L.</creatorcontrib><creatorcontrib>Zang, Xueke</creatorcontrib><creatorcontrib>Lu, Shuguang</creatorcontrib><creatorcontrib>Zhang, Xiang</creatorcontrib><creatorcontrib>Farooq, Usman</creatorcontrib><creatorcontrib>Qiu, Zhaofu</creatorcontrib><creatorcontrib>Sui, Qian</creatorcontrib><title>Enhanced effect of HAH on citric acid-chelated Fe(II)-catalyzed percarbonate for trichloroethene degradation</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>This work demonstrates the impact of hydroxylamine hydrochloride (HAH) addition on enhancing the degradation of trichloroethene (TCE) by the citric acid (CA)-chelated Fe(II)-catalyzed percarbonate (SPC) system. The results of a series of batch-reactor experiments show that TCE removal with HAH addition was increased from approximately 57 to 79% for a CA concentration of 0.1 mM and from 89 to 99.6% for a 0.5 mM concentration. Free-radical probe tests elucidated the existence of hydroxyl radical (HO
•
) and superoxide anion radical (O
2
•-
) in both CA/Fe(II)/SPC and HAH/CA/Fe(II)/SPC systems. However, higher removal rates of radical probe compounds were observed in the HAH/CA/Fe(II)/SPC system, indicating that HAH addition enhanced the generation of both free radicals. In addition, increased contribution of O
2
•-
in the HAH/CA/Fe(II)/SPC system compared to the CA/Fe(II)/SPC system was verified by free-radical scavengers tests. Complete TCE dechlorination was confirmed based on the total mass balance of the released Cl
−
species. Lower concentrations of formic acid were produced in the later stages of the reaction for the HAH/CA/Fe(II)/SPC system, suggesting that HAH addition favors complete TCE mineralization. Studies of the impact of selected groundwater matrix constituents indicate that TCE removal in the HAH/CA/Fe(II)/SPC system is slightly affected by initial solution pH, with higher removal rates under acidic and near neutral conditions. Although HCO
3
−
was observed to have an adverse impact on TCE removal for the HAH/CA/Fe(II)/SPC system, the addition of HAH reduced its inhibitory effect compared to the CA/Fe(II)/SPC system. Finally, TCE removal in actual groundwater was much significant with the addition of HAH to the CA/Fe(II)/SPC system. The study results indicate that HAH amendment has potential to enhance effective remediation of TCE-contaminated groundwater.</description><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Carbonates - chemistry</subject><subject>Chelating Agents - chemistry</subject><subject>Citric acid</subject><subject>Citric Acid - chemistry</subject><subject>Dechlorination</subject><subject>Degradation</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental Restoration and Remediation - methods</subject><subject>Environmental science</subject><subject>Ferrous Compounds - chemistry</subject><subject>Formic acid</subject><subject>Free radicals</subject><subject>Groundwater</subject><subject>Groundwater - analysis</subject><subject>Groundwater pollution</subject><subject>Hydroxyl radicals</subject><subject>Hydroxylamine</subject><subject>Hydroxylamine - chemistry</subject><subject>Iron</subject><subject>Mineralization</subject><subject>pH effects</subject><subject>Research Article</subject><subject>Superoxide</subject><subject>Trichloroethylene</subject><subject>Trichloroethylene - chemistry</subject><subject>Waste Water Technology</subject><subject>Water Management</subject><subject>Water Pollutants, Chemical - chemistry</subject><subject>Water Pollution Control</subject><subject>Water Pollution, Chemical - prevention & control</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kcFrHCEUxqW0JNs0f0AvZaCX9GDqc5xxvBRCSLoLgV7asxh97kyY1a26gfSvr9tNQ1rIRdHv9773Hh8h74GdA2PycwZou54ykLQ-GZWvyAJ6EFQKpV6TBVNCUGiFOCZvc75jjDPF5RE55sMwqLZnCzJfhdEEi65B79GWJvpmebFsYmjsVNJkG2MnR-2IsymVusaz1eoTtaaY-eFX_dhisibdxlDlxsfU7IvGOaaIZcSAjcN1Ms6UKYZ35I03c8bTx_uE_Li--n65pDffvq4uL26o7Zgs1HOjeqyHMgq5A-DMIVPD0NpWOOe9ACuQuV4a4NxXyUoPBiwKZ_vetSfky8F3u7vdoLMYSjKz3qZpY9KDjmbS_yphGvU63utOSq5aWQ3OHg1S_LnDXPRmyhbn2QSMu6yhQrKToERFP_6H3sVdCnW9SnVCdQP_Q8GBsinmnNA_DQNM77PUhyx1zVLvs9T7IT483-Kp4m94FeAHIFcprDE9a_2i628UY6tS</recordid><startdate>20171101</startdate><enddate>20171101</enddate><creator>Fu, Xiaori</creator><creator>Brusseau, Mark L.</creator><creator>Zang, Xueke</creator><creator>Lu, Shuguang</creator><creator>Zhang, Xiang</creator><creator>Farooq, Usman</creator><creator>Qiu, Zhaofu</creator><creator>Sui, Qian</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20171101</creationdate><title>Enhanced effect of HAH on citric acid-chelated Fe(II)-catalyzed percarbonate for trichloroethene degradation</title><author>Fu, Xiaori ; Brusseau, Mark L. ; Zang, Xueke ; Lu, Shuguang ; Zhang, Xiang ; Farooq, Usman ; Qiu, Zhaofu ; Sui, Qian</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c507t-f2a96e2a99a9e2d1120de09883c34ddff41c4e0d67a122fe09c7f1a1ce4dc66d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Carbonates - chemistry</topic><topic>Chelating Agents - chemistry</topic><topic>Citric acid</topic><topic>Citric Acid - chemistry</topic><topic>Dechlorination</topic><topic>Degradation</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental Restoration and Remediation - methods</topic><topic>Environmental science</topic><topic>Ferrous Compounds - chemistry</topic><topic>Formic acid</topic><topic>Free radicals</topic><topic>Groundwater</topic><topic>Groundwater - analysis</topic><topic>Groundwater pollution</topic><topic>Hydroxyl radicals</topic><topic>Hydroxylamine</topic><topic>Hydroxylamine - chemistry</topic><topic>Iron</topic><topic>Mineralization</topic><topic>pH effects</topic><topic>Research Article</topic><topic>Superoxide</topic><topic>Trichloroethylene</topic><topic>Trichloroethylene - chemistry</topic><topic>Waste Water Technology</topic><topic>Water Management</topic><topic>Water Pollutants, Chemical - chemistry</topic><topic>Water Pollution Control</topic><topic>Water Pollution, Chemical - prevention & control</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fu, Xiaori</creatorcontrib><creatorcontrib>Brusseau, Mark L.</creatorcontrib><creatorcontrib>Zang, Xueke</creatorcontrib><creatorcontrib>Lu, Shuguang</creatorcontrib><creatorcontrib>Zhang, Xiang</creatorcontrib><creatorcontrib>Farooq, Usman</creatorcontrib><creatorcontrib>Qiu, Zhaofu</creatorcontrib><creatorcontrib>Sui, Qian</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>ProQuest One Business</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Fu, Xiaori</au><au>Brusseau, Mark L.</au><au>Zang, Xueke</au><au>Lu, Shuguang</au><au>Zhang, Xiang</au><au>Farooq, Usman</au><au>Qiu, Zhaofu</au><au>Sui, Qian</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced effect of HAH on citric acid-chelated Fe(II)-catalyzed percarbonate for trichloroethene degradation</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2017-11-01</date><risdate>2017</risdate><volume>24</volume><issue>31</issue><spage>24318</spage><epage>24326</epage><pages>24318-24326</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>This work demonstrates the impact of hydroxylamine hydrochloride (HAH) addition on enhancing the degradation of trichloroethene (TCE) by the citric acid (CA)-chelated Fe(II)-catalyzed percarbonate (SPC) system. The results of a series of batch-reactor experiments show that TCE removal with HAH addition was increased from approximately 57 to 79% for a CA concentration of 0.1 mM and from 89 to 99.6% for a 0.5 mM concentration. Free-radical probe tests elucidated the existence of hydroxyl radical (HO
•
) and superoxide anion radical (O
2
•-
) in both CA/Fe(II)/SPC and HAH/CA/Fe(II)/SPC systems. However, higher removal rates of radical probe compounds were observed in the HAH/CA/Fe(II)/SPC system, indicating that HAH addition enhanced the generation of both free radicals. In addition, increased contribution of O
2
•-
in the HAH/CA/Fe(II)/SPC system compared to the CA/Fe(II)/SPC system was verified by free-radical scavengers tests. Complete TCE dechlorination was confirmed based on the total mass balance of the released Cl
−
species. Lower concentrations of formic acid were produced in the later stages of the reaction for the HAH/CA/Fe(II)/SPC system, suggesting that HAH addition favors complete TCE mineralization. Studies of the impact of selected groundwater matrix constituents indicate that TCE removal in the HAH/CA/Fe(II)/SPC system is slightly affected by initial solution pH, with higher removal rates under acidic and near neutral conditions. Although HCO
3
−
was observed to have an adverse impact on TCE removal for the HAH/CA/Fe(II)/SPC system, the addition of HAH reduced its inhibitory effect compared to the CA/Fe(II)/SPC system. Finally, TCE removal in actual groundwater was much significant with the addition of HAH to the CA/Fe(II)/SPC system. The study results indicate that HAH amendment has potential to enhance effective remediation of TCE-contaminated groundwater.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>28889360</pmid><doi>10.1007/s11356-017-0070-7</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Carbonates - chemistry Chelating Agents - chemistry Citric acid Citric Acid - chemistry Dechlorination Degradation Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental Restoration and Remediation - methods Environmental science Ferrous Compounds - chemistry Formic acid Free radicals Groundwater Groundwater - analysis Groundwater pollution Hydroxyl radicals Hydroxylamine Hydroxylamine - chemistry Iron Mineralization pH effects Research Article Superoxide Trichloroethylene Trichloroethylene - chemistry Waste Water Technology Water Management Water Pollutants, Chemical - chemistry Water Pollution Control Water Pollution, Chemical - prevention & control |
| title | Enhanced effect of HAH on citric acid-chelated Fe(II)-catalyzed percarbonate for trichloroethene degradation |
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