Enantioselective Rhodium‐Catalyzed Coupling of Arylboronic Acids, 1,3‐Enynes, and Imines by Alkenyl‐to‐Allyl 1,4‐Rhodium(I) Migration

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3‐enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl‐to‐allyl 1,4‐rhodium(I) migration. A chiral rhodium complex catalyzes the highly e...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-12, Vol.56 (51), p.16352-16356
Hauptverfasser:	Callingham, Michael, Partridge, Benjamin M., Lewis, William, Lam, Hon Wai
Format:	Artikel
Sprache:	eng
Schlagworte:	Acids allylation asymmetric catalysis Catalysis Communication Communications Coupling Enantiomers Imines isomerization Migration Rhodium
Online-Zugang:	Volltext
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