Synthesis of 1,2-Bis(trifluoromethylthio)arenes via Aryne Intermediates

A general method for synthesis of 1,2-bis-trifluoro­methyl­thioarenes has been developed. Arynes generated from silyl aryl triflates or halides react with bis­(trifluoro­methyl)­disulfide to afford 1,2-bis-trifluoro­methyl­thioarenes. Aryl, alkyl, ester, halide, and methoxy functionalities are compa...

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Veröffentlicht in:	Organic letters 2017-08, Vol.19 (16), p.4247-4250
Hauptverfasser:	Mesgar, Milad, Daugulis, Olafs
Format:	Artikel
Sprache:	eng
Schlagworte:	aromatic hydrocarbons chemical reactions chemical structure Chemistry Techniques, Synthetic Cyclization Fused-Ring Compounds - chemical synthesis halides Molecular Structure Spiro Compounds - chemical synthesis Structure-Activity Relationship sulfides Sulfides - chemical synthesis
Online-Zugang:	Volltext
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