Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

Catalytic alkylation of C–H bonds is achieved via homolysis of N–H bonds of N -alkyl amides through proton-coupled electron transfer. Functionalizing unactivated aliphatic C–H bonds In two separate reports, Robert Knowles and colleagues, and John Chu and Tomislav Rovis report the selective homolysis...

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