Macrocyclic bis-thioureas catalyze stereospecific glycosylation reactions

Carbohydrates are involved in nearly all aspects of biochemistry, but their complex chemical structures present long-standing practical challenges to their synthesis. In particular, stereochemical outcomes in glycosylation reactions are highly dependent on the steric and electronic properties of cou...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2017-01, Vol.355 (6321), p.162-166
Hauptverfasser:	Park, Yongho, Harper, Kaid C., Kuhl, Nadine, Kwan, Eugene E., Liu, Richard Y., Jacobsen, Eric N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Anchors Carbohydrates Catalysis Catalysts Chemical reactions Chemical synthesis Chlorides Configurations Coupling (molecular) Derivatives Glycosides Glycosides - chemical synthesis Glycosylation Macrocyclic compounds Nucleophiles Stereoisomerism Substitution reactions Sugar Sugars Synthesis (chemistry) Thiourea Thiourea - analogs & derivatives Thiourea derivatives
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