Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier

Conspectus Merging the characteristics of transfer hydrogenation and carbonyl addition, we have developed a new class of catalytic enantioselective C–C bond formations. In these processes, hydrogen transfer between alcohols and π-unsaturated reactants generates carbonyl–organometal pairs that combin...

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Veröffentlicht in:	Accounts of chemical research 2017-09, Vol.50 (9), p.2371-2380
Hauptverfasser:	Kim, Seung Wook, Zhang, Wandi, Krische, Michael J
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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