An efficient eco advanced oxidation process for phenol mineralization using a 2D/3D nanocomposite photocatalyst and visible light irradiations
Nanocomposites (CNTi) with different mass ratios of carbon nitride (C 3 N 4 ) and TiO 2 nanoparticles were prepared hydrothermally. Different characterization techniques were used including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS)...
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| Veröffentlicht in: | Scientific reports 2017-08, Vol.7 (1), p.9898-12, Article 9898 |
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| creator | Al-Kandari, H. Abdullah, A. M. Ahmad, Yahia H. Al-Kandari, S. AlQaradawi, Siham Y. Mohamed, A. M. |
| description | Nanocomposites (CNTi) with different mass ratios of carbon nitride (C
3
N
4
) and TiO
2
nanoparticles were prepared hydrothermally. Different characterization techniques were used including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), transmission electron spectroscopy (TEM) and Brunauer-Emmett-Teller (BET). UV-Vis DRS demonstrated that the CNTi nanocomposites exhibited absorption in the visible light range. A sun light - simulated photoexcitation source was used to study the kinetics of phenol degradation and its intermediates in presence of the as-prepared nanocomposite photocatalysts. These results were compared with studies when TiO
2
nanoparticles were used in the presence and absence of H
2
O
2
and/or O
3
. The photodegradation of phenol was evaluated spectrophotometrically and using the total organic carbon (TOC) measurements. It was observed that the photocatalytic activity of the CNTi nanocomposites was significantly higher than that of TiO
2
nanoparticles. Additionally, spectrophotometry and TOC analyses confirmed that degraded phenol was completely mineralized to CO
2
and H
2
O with the use of CNTi nanocomposites, which was not the case for TiO
2
where several intermediates were formed. Furthermore, when H
2
O
2
and O
3
were simultaneously present, the 0.1% g-C
3
N
4
/TiO
2
nanocomposite showed the highest phenol degradation rate and the degradation percentage was greater than 91.4% within 30 min. |
| doi_str_mv | 10.1038/s41598-017-09826-6 |
| format | Article |
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3
N
4
) and TiO
2
nanoparticles were prepared hydrothermally. Different characterization techniques were used including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), transmission electron spectroscopy (TEM) and Brunauer-Emmett-Teller (BET). UV-Vis DRS demonstrated that the CNTi nanocomposites exhibited absorption in the visible light range. A sun light - simulated photoexcitation source was used to study the kinetics of phenol degradation and its intermediates in presence of the as-prepared nanocomposite photocatalysts. These results were compared with studies when TiO
2
nanoparticles were used in the presence and absence of H
2
O
2
and/or O
3
. The photodegradation of phenol was evaluated spectrophotometrically and using the total organic carbon (TOC) measurements. It was observed that the photocatalytic activity of the CNTi nanocomposites was significantly higher than that of TiO
2
nanoparticles. Additionally, spectrophotometry and TOC analyses confirmed that degraded phenol was completely mineralized to CO
2
and H
2
O with the use of CNTi nanocomposites, which was not the case for TiO
2
where several intermediates were formed. Furthermore, when H
2
O
2
and O
3
were simultaneously present, the 0.1% g-C
3
N
4
/TiO
2
nanocomposite showed the highest phenol degradation rate and the degradation percentage was greater than 91.4% within 30 min.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-017-09826-6</identifier><identifier>PMID: 28851975</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>140/133 ; 140/146 ; 639/301/299/890 ; 639/925/357/1018 ; 704/172/4081 ; Carbon dioxide ; Humanities and Social Sciences ; Hydrogen peroxide ; Intermediates ; Mineralization ; multidisciplinary ; Nanocomposites ; Nanoparticles ; Organic carbon ; Oxidation ; Oxidation process ; Phenols ; Photodegradation ; Photoelectron spectroscopy ; Science ; Science (multidisciplinary) ; Spectrophotometry ; Spectroscopy ; Spectrum analysis ; Titanium dioxide ; Total organic carbon ; X-ray diffraction ; X-rays</subject><ispartof>Scientific reports, 2017-08, Vol.7 (1), p.9898-12, Article 9898</ispartof><rights>The Author(s) 2017</rights><rights>2017. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c474t-7444a4271af3724f5dbe7d183b77fb8125f82049776e317eb360a10de8e032e13</citedby><cites>FETCH-LOGICAL-c474t-7444a4271af3724f5dbe7d183b77fb8125f82049776e317eb360a10de8e032e13</cites><orcidid>0000-0003-0885-8194 ; 0000-0001-8406-9782</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5574923/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5574923/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,861,882,27905,27906,41101,42170,51557,53772,53774</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28851975$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Al-Kandari, H.</creatorcontrib><creatorcontrib>Abdullah, A. M.</creatorcontrib><creatorcontrib>Ahmad, Yahia H.</creatorcontrib><creatorcontrib>Al-Kandari, S.</creatorcontrib><creatorcontrib>AlQaradawi, Siham Y.</creatorcontrib><creatorcontrib>Mohamed, A. M.</creatorcontrib><title>An efficient eco advanced oxidation process for phenol mineralization using a 2D/3D nanocomposite photocatalyst and visible light irradiations</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Nanocomposites (CNTi) with different mass ratios of carbon nitride (C
3
N
4
) and TiO
2
nanoparticles were prepared hydrothermally. Different characterization techniques were used including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), transmission electron spectroscopy (TEM) and Brunauer-Emmett-Teller (BET). UV-Vis DRS demonstrated that the CNTi nanocomposites exhibited absorption in the visible light range. A sun light - simulated photoexcitation source was used to study the kinetics of phenol degradation and its intermediates in presence of the as-prepared nanocomposite photocatalysts. These results were compared with studies when TiO
2
nanoparticles were used in the presence and absence of H
2
O
2
and/or O
3
. The photodegradation of phenol was evaluated spectrophotometrically and using the total organic carbon (TOC) measurements. It was observed that the photocatalytic activity of the CNTi nanocomposites was significantly higher than that of TiO
2
nanoparticles. Additionally, spectrophotometry and TOC analyses confirmed that degraded phenol was completely mineralized to CO
2
and H
2
O with the use of CNTi nanocomposites, which was not the case for TiO
2
where several intermediates were formed. Furthermore, when H
2
O
2
and O
3
were simultaneously present, the 0.1% g-C
3
N
4
/TiO
2
nanocomposite showed the highest phenol degradation rate and the degradation percentage was greater than 91.4% within 30 min.</description><subject>140/133</subject><subject>140/146</subject><subject>639/301/299/890</subject><subject>639/925/357/1018</subject><subject>704/172/4081</subject><subject>Carbon dioxide</subject><subject>Humanities and Social Sciences</subject><subject>Hydrogen peroxide</subject><subject>Intermediates</subject><subject>Mineralization</subject><subject>multidisciplinary</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Organic carbon</subject><subject>Oxidation</subject><subject>Oxidation process</subject><subject>Phenols</subject><subject>Photodegradation</subject><subject>Photoelectron spectroscopy</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Spectrophotometry</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Titanium dioxide</subject><subject>Total organic carbon</subject><subject>X-ray diffraction</subject><subject>X-rays</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kU9rFTEUxQdRbKn9Ai4k4MbNtPk7yWyE0moVCt2065DJ3HkvZSYZk8zD-iH8zKadWp5Cs0ng_s7JPZyqek_wCcFMnSZORKtqTGSNW0WbunlVHVLMRU0Zpa_33gfVcUp3uBxBW07at9UBVUqQVorD6veZRzAMzjrwGYENyPQ74y30KPx0vckueDTHYCElNISI5i34MKLJeYhmdL9WYknOb5BB9OKUXSBvfLBhmkNyGYoi5GBNNuN9ysj4Hu1cct0IaHSbbUYuRtO7R5_0rnozmDHB8dN9VN1-_XJz_q2-ur78fn52VVsuea4l59xwKokZmKR8EH0HsieKdVIOnSJUDKrkb6VsgBEJHWuwIbgHBZhRIOyo-rz6zks3QW9L-JJGz9FNJt7rYJz-d-LdVm_CTgsheUtZMfj0ZBDDjwVS1pNLFsbReAhL0qRlrOVUCVXQj_-hd2GJvsQrlJCqIY182IiulI0hpQjD8zIE64fG9dq4Lo3rx8Z1U0Qf9mM8S_72WwC2AqmM_Abi3t8v2_4BkEm5WQ</recordid><startdate>20170829</startdate><enddate>20170829</enddate><creator>Al-Kandari, H.</creator><creator>Abdullah, A. M.</creator><creator>Ahmad, Yahia H.</creator><creator>Al-Kandari, S.</creator><creator>AlQaradawi, Siham Y.</creator><creator>Mohamed, A. 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M. ; Ahmad, Yahia H. ; Al-Kandari, S. ; AlQaradawi, Siham Y. ; Mohamed, A. 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M.</creatorcontrib><creatorcontrib>Ahmad, Yahia H.</creatorcontrib><creatorcontrib>Al-Kandari, S.</creatorcontrib><creatorcontrib>AlQaradawi, Siham Y.</creatorcontrib><creatorcontrib>Mohamed, A. M.</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Al-Kandari, H.</au><au>Abdullah, A. M.</au><au>Ahmad, Yahia H.</au><au>Al-Kandari, S.</au><au>AlQaradawi, Siham Y.</au><au>Mohamed, A. M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An efficient eco advanced oxidation process for phenol mineralization using a 2D/3D nanocomposite photocatalyst and visible light irradiations</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2017-08-29</date><risdate>2017</risdate><volume>7</volume><issue>1</issue><spage>9898</spage><epage>12</epage><pages>9898-12</pages><artnum>9898</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Nanocomposites (CNTi) with different mass ratios of carbon nitride (C
3
N
4
) and TiO
2
nanoparticles were prepared hydrothermally. Different characterization techniques were used including X-ray diffraction (XRD), UV-Vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), transmission electron spectroscopy (TEM) and Brunauer-Emmett-Teller (BET). UV-Vis DRS demonstrated that the CNTi nanocomposites exhibited absorption in the visible light range. A sun light - simulated photoexcitation source was used to study the kinetics of phenol degradation and its intermediates in presence of the as-prepared nanocomposite photocatalysts. These results were compared with studies when TiO
2
nanoparticles were used in the presence and absence of H
2
O
2
and/or O
3
. The photodegradation of phenol was evaluated spectrophotometrically and using the total organic carbon (TOC) measurements. It was observed that the photocatalytic activity of the CNTi nanocomposites was significantly higher than that of TiO
2
nanoparticles. Additionally, spectrophotometry and TOC analyses confirmed that degraded phenol was completely mineralized to CO
2
and H
2
O with the use of CNTi nanocomposites, which was not the case for TiO
2
where several intermediates were formed. Furthermore, when H
2
O
2
and O
3
were simultaneously present, the 0.1% g-C
3
N
4
/TiO
2
nanocomposite showed the highest phenol degradation rate and the degradation percentage was greater than 91.4% within 30 min.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>28851975</pmid><doi>10.1038/s41598-017-09826-6</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-0885-8194</orcidid><orcidid>https://orcid.org/0000-0001-8406-9782</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Scientific reports, 2017-08, Vol.7 (1), p.9898-12, Article 9898 |
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| language | eng |
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| source | DOAJ Directory of Open Access Journals; Springer Nature OA Free Journals; Nature Free; EZB-FREE-00999 freely available EZB journals; PubMed Central; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry |
| subjects | 140/133 140/146 639/301/299/890 639/925/357/1018 704/172/4081 Carbon dioxide Humanities and Social Sciences Hydrogen peroxide Intermediates Mineralization multidisciplinary Nanocomposites Nanoparticles Organic carbon Oxidation Oxidation process Phenols Photodegradation Photoelectron spectroscopy Science Science (multidisciplinary) Spectrophotometry Spectroscopy Spectrum analysis Titanium dioxide Total organic carbon X-ray diffraction X-rays |
| title | An efficient eco advanced oxidation process for phenol mineralization using a 2D/3D nanocomposite photocatalyst and visible light irradiations |
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