A Unified Approach for the Enantioselective Synthesis of the Brominated Chamigrene Sesquiterpenes

The brominated chamigrene sesquiterpenes constitute a large subclass of bromocyclohexane‐containing natural products, yet no general enantioselective strategy for the synthesis of these small molecules exists. Herein we report a general strategy for accessing this family of secondary metabolites, in...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-09, Vol.55 (38), p.11476-11479
Hauptverfasser:	Burckle, Alexander J., Vasilev, Vasil H., Burns, Noah Z.
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric synthesis Biological Products - chemical synthesis Biological Products - chemistry Bromination Chemical synthesis Crystallography, X-Ray Cycloaddition Reaction Enantiomers Halogenation Metabolites Molecular Conformation Natural products Secondary metabolites Sesquiterpenes Sesquiterpenes - chemical synthesis Sesquiterpenes - chemistry Solvolysis Stereoisomerism terpenes
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