SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate
In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an elec...
Gespeichert in:
| Veröffentlicht in: | Materials 2016-04, Vol.9 (5), p.318-318 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 318 |
|---|---|
| container_issue | 5 |
| container_start_page | 318 |
| container_title | Materials |
| container_volume | 9 |
| creator | Rokosz, Krzysztof Hryniewicz, Tadeusz Matýsek, Dalibor Raaen, Steinar Valíček, Jan Dudek, Łukasz Harničárová, Marta |
| description | In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO₃)₂ (10-600 g/L) in concentrated phosphoric acid H₃PO₄ (98 g/mol) was used. The thickness of the obtained porous surface layer equals about 10 μm, and it consists mainly of titanium phosphates and oxygen with embedded copper ions as a bactericidal agent. The maximum percent of copper in the PEO surface layer was equal to 12.2 ± 0.7 wt % (7.6 ± 0.5 at %), which is the best result that the authors obtained. The top surface layer of all obtained plasma electrolytic oxidation (PEO) coatings consisted most likely mainly of Ti₃(PO₄)₄∙nH₃PO₄ and Cu₃(PO₄)₂∙nH₃PO₄ with a small addition of CuP₂, CuO and Cu₂O. |
| doi_str_mv | 10.3390/ma9050318 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5503094</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1926681332</sourcerecordid><originalsourceid>FETCH-LOGICAL-c502t-636bee070fa1171cd70c14a3cb5cc5946d67f12da2c2a7869846f1b7abde70be3</originalsourceid><addsrcrecordid>eNqFkltrFDEUgINYbFn74B-QgC8KXZvbJJMXoazrBVq3sBV8C2cymTZlJlknGen-B3-0Ka3L6kvzkgPnO18u5yD0ipL3nGtyOoAmFeG0foaOqNZyTrUQz_fiQ3Sc0i0pixeK6RfokNVKcSH4Efq9Xl6c4OXHNYbQ4h-Xa3wWoN8mn3DscL5xeBEh-3Cd8KrJ4INrcQz4ymcIfhowdNmN-LKHNABe9s7mMfbb7C1e3fm2VBbYh72MS8UY7k1FWsLNptR_83mE7F6igw765I4f9xn6_ml5tfgyP199_ro4O5_birA8l1w2zhFFOqBUUdsqYqkAbpvK2koL2UrVUdYCswxULXUtZEcbBU3rFGkcn6EPD97N1AyutS6U43uzGf0A49ZE8ObfTPA35jr-MlX5aKJFEbx9FIzx5-RSNoNP1vU9BBenZKhmUtaUc_Y0WlNJGJelITP05j_0Nk5jaUehVF0rUSBZqHcPlB1jSqPrdvemxNxPhNlNRGFf7z90R_7tP_8DBZmxqw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1788746776</pqid></control><display><type>article</type><title>SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate</title><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><source>PubMed Central Open Access</source><creator>Rokosz, Krzysztof ; Hryniewicz, Tadeusz ; Matýsek, Dalibor ; Raaen, Steinar ; Valíček, Jan ; Dudek, Łukasz ; Harničárová, Marta</creator><creatorcontrib>Rokosz, Krzysztof ; Hryniewicz, Tadeusz ; Matýsek, Dalibor ; Raaen, Steinar ; Valíček, Jan ; Dudek, Łukasz ; Harničárová, Marta</creatorcontrib><description>In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO₃)₂ (10-600 g/L) in concentrated phosphoric acid H₃PO₄ (98 g/mol) was used. The thickness of the obtained porous surface layer equals about 10 μm, and it consists mainly of titanium phosphates and oxygen with embedded copper ions as a bactericidal agent. The maximum percent of copper in the PEO surface layer was equal to 12.2 ± 0.7 wt % (7.6 ± 0.5 at %), which is the best result that the authors obtained. The top surface layer of all obtained plasma electrolytic oxidation (PEO) coatings consisted most likely mainly of Ti₃(PO₄)₄∙nH₃PO₄ and Cu₃(PO₄)₂∙nH₃PO₄ with a small addition of CuP₂, CuO and Cu₂O.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma9050318</identifier><identifier>PMID: 28773443</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Acids ; Biocompatibility ; Coatings ; Copper ; Electrolytes ; Electron microscopes ; Energy ; Geology ; Nitrates ; Oxidation ; Phosphates ; Plasma ; Potash ; Potassium ; Scanning electron microscopy ; Sodium ; Spectrum analysis ; Surface layer ; Titanium ; X-ray photoelectron spectroscopy</subject><ispartof>Materials, 2016-04, Vol.9 (5), p.318-318</ispartof><rights>Copyright MDPI AG 2016</rights><rights>2016 by the authors; 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c502t-636bee070fa1171cd70c14a3cb5cc5946d67f12da2c2a7869846f1b7abde70be3</citedby><cites>FETCH-LOGICAL-c502t-636bee070fa1171cd70c14a3cb5cc5946d67f12da2c2a7869846f1b7abde70be3</cites><orcidid>0000-0002-1040-7213</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5503094/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5503094/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28773443$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Rokosz, Krzysztof</creatorcontrib><creatorcontrib>Hryniewicz, Tadeusz</creatorcontrib><creatorcontrib>Matýsek, Dalibor</creatorcontrib><creatorcontrib>Raaen, Steinar</creatorcontrib><creatorcontrib>Valíček, Jan</creatorcontrib><creatorcontrib>Dudek, Łukasz</creatorcontrib><creatorcontrib>Harničárová, Marta</creatorcontrib><title>SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO₃)₂ (10-600 g/L) in concentrated phosphoric acid H₃PO₄ (98 g/mol) was used. The thickness of the obtained porous surface layer equals about 10 μm, and it consists mainly of titanium phosphates and oxygen with embedded copper ions as a bactericidal agent. The maximum percent of copper in the PEO surface layer was equal to 12.2 ± 0.7 wt % (7.6 ± 0.5 at %), which is the best result that the authors obtained. The top surface layer of all obtained plasma electrolytic oxidation (PEO) coatings consisted most likely mainly of Ti₃(PO₄)₄∙nH₃PO₄ and Cu₃(PO₄)₂∙nH₃PO₄ with a small addition of CuP₂, CuO and Cu₂O.</description><subject>Acids</subject><subject>Biocompatibility</subject><subject>Coatings</subject><subject>Copper</subject><subject>Electrolytes</subject><subject>Electron microscopes</subject><subject>Energy</subject><subject>Geology</subject><subject>Nitrates</subject><subject>Oxidation</subject><subject>Phosphates</subject><subject>Plasma</subject><subject>Potash</subject><subject>Potassium</subject><subject>Scanning electron microscopy</subject><subject>Sodium</subject><subject>Spectrum analysis</subject><subject>Surface layer</subject><subject>Titanium</subject><subject>X-ray photoelectron spectroscopy</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNqFkltrFDEUgINYbFn74B-QgC8KXZvbJJMXoazrBVq3sBV8C2cymTZlJlknGen-B3-0Ka3L6kvzkgPnO18u5yD0ipL3nGtyOoAmFeG0foaOqNZyTrUQz_fiQ3Sc0i0pixeK6RfokNVKcSH4Efq9Xl6c4OXHNYbQ4h-Xa3wWoN8mn3DscL5xeBEh-3Cd8KrJ4INrcQz4ymcIfhowdNmN-LKHNABe9s7mMfbb7C1e3fm2VBbYh72MS8UY7k1FWsLNptR_83mE7F6igw765I4f9xn6_ml5tfgyP199_ro4O5_birA8l1w2zhFFOqBUUdsqYqkAbpvK2koL2UrVUdYCswxULXUtZEcbBU3rFGkcn6EPD97N1AyutS6U43uzGf0A49ZE8ObfTPA35jr-MlX5aKJFEbx9FIzx5-RSNoNP1vU9BBenZKhmUtaUc_Y0WlNJGJelITP05j_0Nk5jaUehVF0rUSBZqHcPlB1jSqPrdvemxNxPhNlNRGFf7z90R_7tP_8DBZmxqw</recordid><startdate>20160427</startdate><enddate>20160427</enddate><creator>Rokosz, Krzysztof</creator><creator>Hryniewicz, Tadeusz</creator><creator>Matýsek, Dalibor</creator><creator>Raaen, Steinar</creator><creator>Valíček, Jan</creator><creator>Dudek, Łukasz</creator><creator>Harničárová, Marta</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1040-7213</orcidid></search><sort><creationdate>20160427</creationdate><title>SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate</title><author>Rokosz, Krzysztof ; Hryniewicz, Tadeusz ; Matýsek, Dalibor ; Raaen, Steinar ; Valíček, Jan ; Dudek, Łukasz ; Harničárová, Marta</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c502t-636bee070fa1171cd70c14a3cb5cc5946d67f12da2c2a7869846f1b7abde70be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Acids</topic><topic>Biocompatibility</topic><topic>Coatings</topic><topic>Copper</topic><topic>Electrolytes</topic><topic>Electron microscopes</topic><topic>Energy</topic><topic>Geology</topic><topic>Nitrates</topic><topic>Oxidation</topic><topic>Phosphates</topic><topic>Plasma</topic><topic>Potash</topic><topic>Potassium</topic><topic>Scanning electron microscopy</topic><topic>Sodium</topic><topic>Spectrum analysis</topic><topic>Surface layer</topic><topic>Titanium</topic><topic>X-ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rokosz, Krzysztof</creatorcontrib><creatorcontrib>Hryniewicz, Tadeusz</creatorcontrib><creatorcontrib>Matýsek, Dalibor</creatorcontrib><creatorcontrib>Raaen, Steinar</creatorcontrib><creatorcontrib>Valíček, Jan</creatorcontrib><creatorcontrib>Dudek, Łukasz</creatorcontrib><creatorcontrib>Harničárová, Marta</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rokosz, Krzysztof</au><au>Hryniewicz, Tadeusz</au><au>Matýsek, Dalibor</au><au>Raaen, Steinar</au><au>Valíček, Jan</au><au>Dudek, Łukasz</au><au>Harničárová, Marta</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2016-04-27</date><risdate>2016</risdate><volume>9</volume><issue>5</issue><spage>318</spage><epage>318</epage><pages>318-318</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>In the paper, the Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Photoelectron Spectroscopy (XPS) results of the surface layer formed on pure titanium after plasma electrolytic oxidation (micro arc oxidation) at the voltage of 450 V are shown. As an electrolyte, the mixture of copper nitrate Cu(NO₃)₂ (10-600 g/L) in concentrated phosphoric acid H₃PO₄ (98 g/mol) was used. The thickness of the obtained porous surface layer equals about 10 μm, and it consists mainly of titanium phosphates and oxygen with embedded copper ions as a bactericidal agent. The maximum percent of copper in the PEO surface layer was equal to 12.2 ± 0.7 wt % (7.6 ± 0.5 at %), which is the best result that the authors obtained. The top surface layer of all obtained plasma electrolytic oxidation (PEO) coatings consisted most likely mainly of Ti₃(PO₄)₄∙nH₃PO₄ and Cu₃(PO₄)₂∙nH₃PO₄ with a small addition of CuP₂, CuO and Cu₂O.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>28773443</pmid><doi>10.3390/ma9050318</doi><tpages>1</tpages><orcidid>https://orcid.org/0000-0002-1040-7213</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2016-04, Vol.9 (5), p.318-318 |
| issn | 1996-1944 1996-1944 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5503094 |
| source | MDPI - Multidisciplinary Digital Publishing Institute; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Acids Biocompatibility Coatings Copper Electrolytes Electron microscopes Energy Geology Nitrates Oxidation Phosphates Plasma Potash Potassium Scanning electron microscopy Sodium Spectrum analysis Surface layer Titanium X-ray photoelectron spectroscopy |
| title | SEM, EDS and XPS Analysis of the Coatings Obtained on Titanium after Plasma Electrolytic Oxidation in Electrolytes Containing Copper Nitrate |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-28T23%3A15%3A06IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=SEM,%20EDS%20and%20XPS%20Analysis%20of%20the%20Coatings%20Obtained%20on%20Titanium%20after%20Plasma%20Electrolytic%20Oxidation%20in%20Electrolytes%20Containing%20Copper%20Nitrate&rft.jtitle=Materials&rft.au=Rokosz,%20Krzysztof&rft.date=2016-04-27&rft.volume=9&rft.issue=5&rft.spage=318&rft.epage=318&rft.pages=318-318&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma9050318&rft_dat=%3Cproquest_pubme%3E1926681332%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1788746776&rft_id=info:pmid/28773443&rfr_iscdi=true |