Crystal structure of (-)-methyl ( R , E )-4-[(2 R ,4 R )-2-amino-2-tri-chloro-methyl-1,3-dioxolan-4-yl]-4-hy-droxy-2-methyl-but-2-enoate

Crystal structure of (-)-methyl ( R , E )-4-[(2 R ,4 R )-2-amino-2-tri-chloro-methyl-1,3-dioxolan-4-yl]-4-hy-droxy-2-methyl-but-2-enoate

In the title compound, C H Cl NO , the five-membered dioxolane ring adopts an envelope conformation with the C atom bonded to the butenoate side chain as the flap. It deviates from the mean plane of the other atoms in the ring by 0.446 (6) Å. In the crystal, mol-ecules are connected by O-H⋯O hydroge...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-07, Vol.73 (Pt 7), p.983-986
Hauptverfasser: Oishi, Takeshi, Kidena, Mayu, Sugai, Tomoya, Sato, Takaaki, Chida, Noritaka
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container_issue Pt 7
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container_title Acta crystallographica. Section E, Crystallographic communications
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creator Oishi, Takeshi
Kidena, Mayu
Sugai, Tomoya
Sato, Takaaki
Chida, Noritaka
description In the title compound, C H Cl NO , the five-membered dioxolane ring adopts an envelope conformation with the C atom bonded to the butenoate side chain as the flap. It deviates from the mean plane of the other atoms in the ring by 0.446 (6) Å. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds into helical chains running along the axis direction. The chains are linked into a sheet structure parallel to (001) by an N-H⋯O hydrogen bond. These classical hydrogen bonds enclose an (24) graph-set motif in the sheet structure. Furthermore, a weak inter-molecular C-H⋯Cl inter-action expands the sheet structures into a three-dimensional network.
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title Crystal structure of (-)-methyl ( R , E )-4-[(2 R ,4 R )-2-amino-2-tri-chloro-methyl-1,3-dioxolan-4-yl]-4-hy-droxy-2-methyl-but-2-enoate
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