A new example of intra-molecular C-H⋯Ni anagostic inter-actions: synthesis, crystal structure and Hirshfeld analysis of cis -bis-[4-methyl-2-(1,2,3,4-tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbo-thio-amidato-κ 2 N 1 , S ]nickel(II) di-methyl-formamide monosolvate

The reaction of Ni acetate tetra-hydrate with 4-methyl-2-(1,2,3,4-tetra-hydro-naphthalen-1-yl-idene)hydrazinecarbo-thio-amide in a 2:1 molar ratio and recrystallization from di-methyl-formamide yielded the title compound, [Ni(C H N S) ]·C H NO. The ligands act as monoanionic κ , -donors, forming fiv...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-06, Vol.73 (Pt 6), p.859-863
Hauptverfasser: de Oliveira, Adriano Bof, Beck, Johannes, Mellone, Sônia Elizabeth Brown S, Daniels, Jörg
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Sprache:eng
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