Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes
The polyaniline/single-walled carbon nanotubes (PANI/SWNTs) composites with a content of SWNTs varying from 8 wt% to 32 wt% were synthesized using a solid-state synthesis method. The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-...
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| Veröffentlicht in: | Materials 2012-07, Vol.5 (7), p.1219-1231 |
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| creator | Abdiryim, Tursun Ubul, Aminam Jamal, Ruxangul Rahman, Adalet |
| description | The polyaniline/single-walled carbon nanotubes (PANI/SWNTs) composites with a content of SWNTs varying from 8 wt% to 32 wt% were synthesized using a solid-state synthesis method. The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-visible (UV-vis) absorption spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical performances of the composites were investigated by galvanostatic charge–discharge and cycling stability measurements. The structure and properties of PANI/SWNTs were compared with those of PANI/multi-walled carbon nanotubes (PANI/MWNTs) prepared under the same polymerization conditions. The results from FTIR and UV-vis spectra showed that the composites with SWNTs displayed a higher oxidation and doping degree than pure PANI, which is similar to that of PANI/MWNTs. The morphological studies revealed that PANI/SWNTs did not display any rod-like and granular-like features, which appeared in PANI/MWNTs. The galvanostatic charge–discharge measurements indicated that the specific capacitance of PANI/SWNTs is not higher than that of PANI/MWNTs, but the PANI/SWNTs exhibited higher cycling stability and more stable electrochemical behavior in neutral and alkaline electrolytes than PANI/MWNTs. |
| doi_str_mv | 10.3390/ma5071219 |
| format | Article |
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The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-visible (UV-vis) absorption spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical performances of the composites were investigated by galvanostatic charge–discharge and cycling stability measurements. The structure and properties of PANI/SWNTs were compared with those of PANI/multi-walled carbon nanotubes (PANI/MWNTs) prepared under the same polymerization conditions. The results from FTIR and UV-vis spectra showed that the composites with SWNTs displayed a higher oxidation and doping degree than pure PANI, which is similar to that of PANI/MWNTs. The morphological studies revealed that PANI/SWNTs did not display any rod-like and granular-like features, which appeared in PANI/MWNTs. The galvanostatic charge–discharge measurements indicated that the specific capacitance of PANI/SWNTs is not higher than that of PANI/MWNTs, but the PANI/SWNTs exhibited higher cycling stability and more stable electrochemical behavior in neutral and alkaline electrolytes than PANI/MWNTs.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma5071219</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon ; Fourier transforms ; Morphology ; Polymerization ; Polymers ; Transmission electron microscopy</subject><ispartof>Materials, 2012-07, Vol.5 (7), p.1219-1231</ispartof><rights>Copyright MDPI AG 2012</rights><rights>2012 by the authors. 2012</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c347t-576b5afa8ff6ca2e0f8d847d7d4e3b44f0400880b44b89b87db06625be4ef9e83</citedby><cites>FETCH-LOGICAL-c347t-576b5afa8ff6ca2e0f8d847d7d4e3b44f0400880b44b89b87db06625be4ef9e83</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5448897/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5448897/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids></links><search><creatorcontrib>Abdiryim, Tursun</creatorcontrib><creatorcontrib>Ubul, Aminam</creatorcontrib><creatorcontrib>Jamal, Ruxangul</creatorcontrib><creatorcontrib>Rahman, Adalet</creatorcontrib><title>Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes</title><title>Materials</title><description>The polyaniline/single-walled carbon nanotubes (PANI/SWNTs) composites with a content of SWNTs varying from 8 wt% to 32 wt% were synthesized using a solid-state synthesis method. The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-visible (UV-vis) absorption spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical performances of the composites were investigated by galvanostatic charge–discharge and cycling stability measurements. The structure and properties of PANI/SWNTs were compared with those of PANI/multi-walled carbon nanotubes (PANI/MWNTs) prepared under the same polymerization conditions. The results from FTIR and UV-vis spectra showed that the composites with SWNTs displayed a higher oxidation and doping degree than pure PANI, which is similar to that of PANI/MWNTs. The morphological studies revealed that PANI/SWNTs did not display any rod-like and granular-like features, which appeared in PANI/MWNTs. The galvanostatic charge–discharge measurements indicated that the specific capacitance of PANI/SWNTs is not higher than that of PANI/MWNTs, but the PANI/SWNTs exhibited higher cycling stability and more stable electrochemical behavior in neutral and alkaline electrolytes than PANI/MWNTs.</description><subject>Carbon</subject><subject>Fourier transforms</subject><subject>Morphology</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Transmission electron microscopy</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kV9LwzAUxYsoOOYe_AYFn3yoS9u0TXwQRvEfzD9QxceQtMmWkSYzSSf9BH5tKxvDPXhf7oF7-N0DJwjOY3CVphhMW5qBIk5ifBSMYozzKMYQHv_Rp8HEuRUYJk1jlOBR8F0ZJZuo8tTzsOq1X3InXWhE-GpUT7VUUvNpJfVC8eiDKsWbsKSWGR0-U218x7i7Dmdhado1tdTLzYDxXdOHX9IvDyBPnfLyP8ZZcCKocnyy2-Pg_e72rXyI5i_3j-VsHtUpLHyUFTnLqKBIiLymCQcCNQgWTdFAnjIIBYAAIAQGyRBmqGgYyPMkYxxygTlKx8HNlrvuWMubmmtvqSJrK1tqe2KoJIcXLZdkYTYkgxAhXAyAix3Ams-OO09WprN6yEziLBksuIBwcF1uXbU1zlku9h9iQH67Ivuu0h99iYob</recordid><startdate>20120716</startdate><enddate>20120716</enddate><creator>Abdiryim, Tursun</creator><creator>Ubul, Aminam</creator><creator>Jamal, Ruxangul</creator><creator>Rahman, Adalet</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>5PM</scope></search><sort><creationdate>20120716</creationdate><title>Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes</title><author>Abdiryim, Tursun ; Ubul, Aminam ; Jamal, Ruxangul ; Rahman, Adalet</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c347t-576b5afa8ff6ca2e0f8d847d7d4e3b44f0400880b44b89b87db06625be4ef9e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Carbon</topic><topic>Fourier transforms</topic><topic>Morphology</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Transmission electron microscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Abdiryim, Tursun</creatorcontrib><creatorcontrib>Ubul, Aminam</creatorcontrib><creatorcontrib>Jamal, Ruxangul</creatorcontrib><creatorcontrib>Rahman, Adalet</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Abdiryim, Tursun</au><au>Ubul, Aminam</au><au>Jamal, Ruxangul</au><au>Rahman, Adalet</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes</atitle><jtitle>Materials</jtitle><date>2012-07-16</date><risdate>2012</risdate><volume>5</volume><issue>7</issue><spage>1219</spage><epage>1231</epage><pages>1219-1231</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>The polyaniline/single-walled carbon nanotubes (PANI/SWNTs) composites with a content of SWNTs varying from 8 wt% to 32 wt% were synthesized using a solid-state synthesis method. The structure and morphology of the samples were characterized by fourier transform infrared (FTIR) spectra, ultraviolet-visible (UV-vis) absorption spectra, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The electrochemical performances of the composites were investigated by galvanostatic charge–discharge and cycling stability measurements. The structure and properties of PANI/SWNTs were compared with those of PANI/multi-walled carbon nanotubes (PANI/MWNTs) prepared under the same polymerization conditions. The results from FTIR and UV-vis spectra showed that the composites with SWNTs displayed a higher oxidation and doping degree than pure PANI, which is similar to that of PANI/MWNTs. The morphological studies revealed that PANI/SWNTs did not display any rod-like and granular-like features, which appeared in PANI/MWNTs. The galvanostatic charge–discharge measurements indicated that the specific capacitance of PANI/SWNTs is not higher than that of PANI/MWNTs, but the PANI/SWNTs exhibited higher cycling stability and more stable electrochemical behavior in neutral and alkaline electrolytes than PANI/MWNTs.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/ma5071219</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 1996-1944 |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Carbon Fourier transforms Morphology Polymerization Polymers Transmission electron microscopy |
| title | Solid-State Synthesis of Polyaniline/Single-Walled Carbon Nanotubes: A Comparative Study with Polyaniline/Multi-Walled Carbon Nanotubes |
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