Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer
Amorphous Spherical Carbon with Nitrogen (SCN) active carbon has been prepared by carbonization of poly(vinylpyridine-divinylbenzene) (PVPDVB) copolymer. The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (S...
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| Veröffentlicht in: | Materials 2009-09, Vol.2 (3), p.1239-1251 |
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| creator | Khavryuchenko, Volodymyr D. Khavryuchenko, Oleksiy V. Shkilnyy, Andriy I. Stratiichuk, Denys A. Lisnyak, Vladyslav V. |
| description | Amorphous Spherical Carbon with Nitrogen (SCN) active carbon has been prepared by carbonization of poly(vinylpyridine-divinylbenzene) (PVPDVB) copolymer. The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) studies of the resulting product have conformed the QC computation results. Great structural similarity is found both at the nano- and micro-levels between the N-doped SCN carbon and its pure carbonic SKS analog. |
| doi_str_mv | 10.3390/ma2031239 |
| format | Article |
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The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) studies of the resulting product have conformed the QC computation results. Great structural similarity is found both at the nano- and micro-levels between the N-doped SCN carbon and its pure carbonic SKS analog.</description><subject>Carbon</subject><subject>Graphite</subject><subject>Nitrogen</subject><subject>Optimization</subject><subject>Scanning electron microscopy</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNpVkdtq3DAQhk1poSHNRd9A0Jss1I1k2ZZ1Uwju9gA5ld1eC1kexwqW5MryFucN-1bVbg40czMzzD_fPzBJ8p7gT5RyfGZkhinJKH-VHBHOy5TwPH_9X_02OZmmOxyDUlJl_Cj5W_fSSxXA63sZtLOoWdBmffkRbdeXSNoW_ZylDbNJ6x6MVnJAG23m4aCdkOtQ6AFtxj4C9sNa-iZC_ujQoysdvLsFi0439dUKnaugd_CkuPGunRW0e79t3DZx-QsoZ0Y36cMhkX3jhuV0p-0yjIvXrbaQtvrQN2DvwcIK1W6MIgP-XfKmk8MEJ4_5OPn1db2tv6cX199-1OcXqaI5CynnpMR5Vqoya1jF2oxwSYGUhLMGCtVSXuAOOk44wUQ2mMkcpCIsbzhUjDN6nHx-4I5zY6BVYIOXgxi9NtIvwkktXk6s7sWt24kizwtGswj48Ajw7vcMUxB3bvY23ixIkVUVo9XBZvWgUt5Nk4fu2YFgsf-2eP42_QchXKCQ</recordid><startdate>20090907</startdate><enddate>20090907</enddate><creator>Khavryuchenko, Volodymyr D.</creator><creator>Khavryuchenko, Oleksiy V.</creator><creator>Shkilnyy, Andriy I.</creator><creator>Stratiichuk, Denys A.</creator><creator>Lisnyak, Vladyslav V.</creator><general>MDPI AG</general><general>Molecular Diversity Preservation International</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>5PM</scope></search><sort><creationdate>20090907</creationdate><title>Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer</title><author>Khavryuchenko, Volodymyr D. ; 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The PVPDVB dehydrogenation copolymer has been quantum chemically (QC) simulated using cluster and periodic models. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) studies of the resulting product have conformed the QC computation results. Great structural similarity is found both at the nano- and micro-levels between the N-doped SCN carbon and its pure carbonic SKS analog.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/ma2031239</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1996-1944 |
| ispartof | Materials, 2009-09, Vol.2 (3), p.1239-1251 |
| issn | 1996-1944 1996-1944 |
| language | eng |
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| source | MDPI - Multidisciplinary Digital Publishing Institute; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry; PubMed Central Open Access |
| subjects | Carbon Graphite Nitrogen Optimization Scanning electron microscopy |
| title | Characterization by SEM, TEM and Quantum-Chemical Simulations of the Spherical Carbon with Nitrogen (SCN) Active Carbon Produced by Thermal Decomposition of Poly(vinylpyridine-divinylbenzene) Copolymer |
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