Interrogating the Lewis Acidity of Metal Sites in Beta Zeolites with 15N Pyridine Adsorption Coupled with MAS NMR Spectroscopy

The Lewis acidity of isolated framework metal sites in Beta zeolites was characterized with 15N isotopically labeled pyridine adsorption coupled with magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. The 15N chemical shift of adsorbed pyridine was found to scale with the acid c...

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Veröffentlicht in:Journal of physical chemistry. C 2016-12, Vol.120 (50), p.28533-28544
Hauptverfasser: Gunther, William R, Michaelis, Vladimir K, Griffin, Robert G, Román-Leshkov, Yuriy
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Sprache:eng
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