Crystal structure of methyl (4 R )-4-(4-meth-oxy-benzo-yl)-4-{[(1 R )-1-phenyl-eth-yl]carbamo-yl}butano-ate

Crystal structure of methyl (4 R )-4-(4-meth-oxy-benzo-yl)-4-{[(1 R )-1-phenyl-eth-yl]carbamo-yl}butano-ate

The title compound, C H NO , was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C-N-C(=O)-C torsion angle is 176.1 (6)°. In the crystal, amide- (4) N-H⋯O and reinforcing C-H⋯O hydrogen bonds lin...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2017-04, Vol.73 (Pt 4), p.503-506
Hauptverfasser: Manchado, Alejandro, Salgado, Mateo M, Vicente, Álvaro, Díez, David, Sanz, Francisca, Garrido, Narciso M
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container_end_page 506
container_issue Pt 4
container_start_page 503
container_title Acta crystallographica. Section E, Crystallographic communications
container_volume 73
creator Manchado, Alejandro
Salgado, Mateo M
Vicente, Álvaro
Díez, David
Sanz, Francisca
Garrido, Narciso M
description The title compound, C H NO , was prepared by CAN [cerium(IV) ammonium nitrate] oxidation of the corresponding β-lactam. The dihedral angle between the benzene rings is 13.3 (4)° and the C-N-C(=O)-C torsion angle is 176.1 (6)°. In the crystal, amide- (4) N-H⋯O and reinforcing C-H⋯O hydrogen bonds link the mol-ecules into infinite [010] chains. Further C-H⋯O hydrogen bonds cross-link the chains in the -axis direction.
doi_str_mv 10.1107/S2056989017003607
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title Crystal structure of methyl (4 R )-4-(4-meth-oxy-benzo-yl)-4-{[(1 R )-1-phenyl-eth-yl]carbamo-yl}butano-ate
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