Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes† †Electronic supplementary information (ESI) available: Experimental procedures, spectroscopic data and copies of 1H and 13C NMR spectra. See DOI: 10.1039/c6sc02617f Click here for additional data file

We functionalize cyclobutene species into polysubstituted metalated cyclobutanes through the Dzhemilev reaction. The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subs...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-08, Vol.8 (1), p.334-339
Hauptverfasser:	Roy, Sudipta Raha, Eijsberg, Hendrik, Bruffaerts, Jeffrey, Marek, Ilan
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry
Online-Zugang:	Volltext
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