Toward production of pure 13C hyperpolarized metabolites using heterogeneous parahydrogen-induced polarization of ethyl[1-13C]acetate

Here, we report the production of 13C-hyperpolarized ethyl acetate via heterogeneously catalyzed pairwise addition of parahydrogen to vinyl acetate over TiO2-supported rhodium nanoparticles, followed by magnetic field cycling. Importantly, the hyperpolarization is demonstrated even at the natural ab...

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Veröffentlicht in:	RSC advances 2016-01, Vol.6 (74), p.69728-69732
Hauptverfasser:	Kovtunov, K V, Barskiy, DA, Salnikov, O G, Shchepin, R V, Coffey, A M, Kovtunova, L M, Bukhtiyarov, VI, Koptyug, I V, Chekmenev, E Y
Format:	Artikel
Sprache:	eng
Schlagworte:	carbon catalysts Cycles ethyl acetate Isotopes Liquids Magnetic fields metabolites Nanoparticles Rhodium stable isotopes Titanium dioxide Vinyl acetate
Online-Zugang:	Volltext
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