Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C–H Bonds by Silver-Mediated C–H Activation: A Synthetic and Mechanistic Investigation

We describe a method for the site-selective construction of a C­(aryl)–C­(sp3) bond by the palladium-catalyzed direct allylation of arenes with allylic pivalates in the presence of AgOPiv to afford the linear (E)-allylated arene with excellent regio­selectivity; this reaction occurs with arenes that...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-11, Vol.138 (46), p.15278-15284
Hauptverfasser:	Lee, Sarah Yunmi, Hartwig, John F
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl Compounds - chemical synthesis Allyl Compounds - chemistry aromatic hydrocarbons Catalysis chemical bonding Molecular Structure Palladium - chemistry phosphine Silver - chemistry stereochemistry
Online-Zugang:	Volltext
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