Crystal Fluidity Reflected by Fast Rotational Motion at the Core, Branches, and Peripheral Aromatic Groups of a Dendrimeric Molecular Rotor

Low packing densities are key structural features of amphidynamic crystals built with static and mobile components. Here we report a loosely packed crystal of dendrimeric rotor 2 and the fast dynamics of all its aromatic groups, both resulting from the hyperbranched structure of the molecule. Compou...

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Veröffentlicht in:	Journal of the American Chemical Society 2016-04, Vol.138 (13), p.4650-4656
Hauptverfasser:	Jiang, Xing, O’Brien, Zachary J, Yang, Song, Lai, Lan Huong, Buenaflor, Jeffrey, Tan, Colleen, Khan, Saeed, Houk, K. N, Garcia-Garibay, Miguel A
Format:	Artikel
Sprache:	eng
Schlagworte:	Crystallography, X-Ray Dendrimers - chemistry Liquid Crystals Models, Molecular Molecular Conformation Nuclear Magnetic Resonance, Biomolecular Temperature
Online-Zugang:	Volltext
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