Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser
We have successfully determined the internuclear distance of I 2 molecules in an alignment laser field by applying our molecular structure determination methodology to an I 2 p X-ray photoelectron diffraction profile observed with femtosecond X-ray free electron laser pulses. Using this methodology,...
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| Veröffentlicht in: | Scientific reports 2016-12, Vol.6 (1), p.38654-38654, Article 38654 |
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| creator | Minemoto, Shinichirou Teramoto, Takahiro Akagi, Hiroshi Fujikawa, Takashi Majima, Takuya Nakajima, Kyo Niki, Kaori Owada, Shigeki Sakai, Hirofumi Togashi, Tadashi Tono, Kensuke Tsuru, Shota Wada, Ken Yabashi, Makina Yoshida, Shintaro Yagishita, Akira |
| description | We have successfully determined the internuclear distance of I
2
molecules in an alignment laser field by applying our molecular structure determination methodology to an I 2
p
X-ray photoelectron diffraction profile observed with femtosecond X-ray free electron laser pulses. Using this methodology, we have found that the internuclear distance of the sample I
2
molecules in an alignment Nd:YAG laser field of 6 × 10
11
W/cm
2
is elongated by from 0.18 to 0.30 Å “in average” relatively to the equilibrium internuclear distance of 2.666 Å. Thus, the present experiment constitutes a critical step towards the goal of femtosecond imaging of chemical reactions and opens a new direction for the study of ultrafast chemical reaction in the gas phase. |
| doi_str_mv | 10.1038/srep38654 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5146652</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1847890213</sourcerecordid><originalsourceid>FETCH-LOGICAL-c548t-45cb5f04130685f2baa6693c503fc4632eebf00550a3172b8535160fd73ec2243</originalsourceid><addsrcrecordid>eNplkdtqHSEUhqW0NGE3F32BIOSmKUzrcQ43hRB6gkAvmkDvxHGWOwZHd9QJ5B360DXZ6WanFUFhfX6uxY_QW0o-UML7jznBhvetFC_QISNCNowz9nLvfoCOcr4hdUk2CDq8RgesG7joB3qIfv8saTFlSYAnKJBmF3RxMeBo8Rw9mMVDxi5gXbd36zBDKNjrDAlbB37C4z22MJeYwcQw4c11LBHqw5KqZXLWJm0ejUt2Yf3g-dUkXR8lgGYHPhrfoFdW-wxHT-cKXX35fHn-rbn48fX7-dlFY6ToSyOkGaUlgnLS9tKyUeu2HbiRhFsjWs4ARlunlURz2rGxl1zSltip42AYE3yFPm29m2WcYTJ1pKS92iQ363SvonbqeSW4a7WOd0pS0baSVcG7J0GKtwvkomaXDXivA8QlK9qLrh8Io7yiJ_-gN3FJoY5XqWHgHSW1vxU63VImxVwTtbtmKFEPMatdzJU93u9-R_4NtQLvt0CupbCGtPflf7Y_lG60Sg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1899371085</pqid></control><display><type>article</type><title>Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser</title><source>SpringerOpen</source><source>Nature_OA刊</source><source>Full-Text Journals in Chemistry (Open access)</source><source>PubMed Central</source><source>Directory of Open Access Journals</source><source>EZB Electronic Journals Library</source><creator>Minemoto, Shinichirou ; Teramoto, Takahiro ; Akagi, Hiroshi ; Fujikawa, Takashi ; Majima, Takuya ; Nakajima, Kyo ; Niki, Kaori ; Owada, Shigeki ; Sakai, Hirofumi ; Togashi, Tadashi ; Tono, Kensuke ; Tsuru, Shota ; Wada, Ken ; Yabashi, Makina ; Yoshida, Shintaro ; Yagishita, Akira</creator><creatorcontrib>Minemoto, Shinichirou ; Teramoto, Takahiro ; Akagi, Hiroshi ; Fujikawa, Takashi ; Majima, Takuya ; Nakajima, Kyo ; Niki, Kaori ; Owada, Shigeki ; Sakai, Hirofumi ; Togashi, Tadashi ; Tono, Kensuke ; Tsuru, Shota ; Wada, Ken ; Yabashi, Makina ; Yoshida, Shintaro ; Yagishita, Akira</creatorcontrib><description>We have successfully determined the internuclear distance of I
2
molecules in an alignment laser field by applying our molecular structure determination methodology to an I 2
p
X-ray photoelectron diffraction profile observed with femtosecond X-ray free electron laser pulses. Using this methodology, we have found that the internuclear distance of the sample I
2
molecules in an alignment Nd:YAG laser field of 6 × 10
11
W/cm
2
is elongated by from 0.18 to 0.30 Å “in average” relatively to the equilibrium internuclear distance of 2.666 Å. Thus, the present experiment constitutes a critical step towards the goal of femtosecond imaging of chemical reactions and opens a new direction for the study of ultrafast chemical reaction in the gas phase.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep38654</identifier><identifier>PMID: 27934891</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/638/440/94 ; 639/766/36/1121 ; Chemical reactions ; Diffraction ; Humanities and Social Sciences ; Lasers ; multidisciplinary ; Science</subject><ispartof>Scientific reports, 2016-12, Vol.6 (1), p.38654-38654, Article 38654</ispartof><rights>The Author(s) 2016</rights><rights>Copyright Nature Publishing Group Dec 2016</rights><rights>Copyright © 2016, The Author(s) 2016 The Author(s)</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c548t-45cb5f04130685f2baa6693c503fc4632eebf00550a3172b8535160fd73ec2243</citedby><cites>FETCH-LOGICAL-c548t-45cb5f04130685f2baa6693c503fc4632eebf00550a3172b8535160fd73ec2243</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5146652/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC5146652/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,315,728,781,785,865,886,27928,27929,41124,42193,51580,53795,53797</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27934891$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Minemoto, Shinichirou</creatorcontrib><creatorcontrib>Teramoto, Takahiro</creatorcontrib><creatorcontrib>Akagi, Hiroshi</creatorcontrib><creatorcontrib>Fujikawa, Takashi</creatorcontrib><creatorcontrib>Majima, Takuya</creatorcontrib><creatorcontrib>Nakajima, Kyo</creatorcontrib><creatorcontrib>Niki, Kaori</creatorcontrib><creatorcontrib>Owada, Shigeki</creatorcontrib><creatorcontrib>Sakai, Hirofumi</creatorcontrib><creatorcontrib>Togashi, Tadashi</creatorcontrib><creatorcontrib>Tono, Kensuke</creatorcontrib><creatorcontrib>Tsuru, Shota</creatorcontrib><creatorcontrib>Wada, Ken</creatorcontrib><creatorcontrib>Yabashi, Makina</creatorcontrib><creatorcontrib>Yoshida, Shintaro</creatorcontrib><creatorcontrib>Yagishita, Akira</creatorcontrib><title>Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>We have successfully determined the internuclear distance of I
2
molecules in an alignment laser field by applying our molecular structure determination methodology to an I 2
p
X-ray photoelectron diffraction profile observed with femtosecond X-ray free electron laser pulses. Using this methodology, we have found that the internuclear distance of the sample I
2
molecules in an alignment Nd:YAG laser field of 6 × 10
11
W/cm
2
is elongated by from 0.18 to 0.30 Å “in average” relatively to the equilibrium internuclear distance of 2.666 Å. Thus, the present experiment constitutes a critical step towards the goal of femtosecond imaging of chemical reactions and opens a new direction for the study of ultrafast chemical reaction in the gas phase.</description><subject>639/638/440/94</subject><subject>639/766/36/1121</subject><subject>Chemical reactions</subject><subject>Diffraction</subject><subject>Humanities and Social Sciences</subject><subject>Lasers</subject><subject>multidisciplinary</subject><subject>Science</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNplkdtqHSEUhqW0NGE3F32BIOSmKUzrcQ43hRB6gkAvmkDvxHGWOwZHd9QJ5B360DXZ6WanFUFhfX6uxY_QW0o-UML7jznBhvetFC_QISNCNowz9nLvfoCOcr4hdUk2CDq8RgesG7joB3qIfv8saTFlSYAnKJBmF3RxMeBo8Rw9mMVDxi5gXbd36zBDKNjrDAlbB37C4z22MJeYwcQw4c11LBHqw5KqZXLWJm0ejUt2Yf3g-dUkXR8lgGYHPhrfoFdW-wxHT-cKXX35fHn-rbn48fX7-dlFY6ToSyOkGaUlgnLS9tKyUeu2HbiRhFsjWs4ARlunlURz2rGxl1zSltip42AYE3yFPm29m2WcYTJ1pKS92iQ363SvonbqeSW4a7WOd0pS0baSVcG7J0GKtwvkomaXDXivA8QlK9qLrh8Io7yiJ_-gN3FJoY5XqWHgHSW1vxU63VImxVwTtbtmKFEPMatdzJU93u9-R_4NtQLvt0CupbCGtPflf7Y_lG60Sg</recordid><startdate>20161209</startdate><enddate>20161209</enddate><creator>Minemoto, Shinichirou</creator><creator>Teramoto, Takahiro</creator><creator>Akagi, Hiroshi</creator><creator>Fujikawa, Takashi</creator><creator>Majima, Takuya</creator><creator>Nakajima, Kyo</creator><creator>Niki, Kaori</creator><creator>Owada, Shigeki</creator><creator>Sakai, Hirofumi</creator><creator>Togashi, Tadashi</creator><creator>Tono, Kensuke</creator><creator>Tsuru, Shota</creator><creator>Wada, Ken</creator><creator>Yabashi, Makina</creator><creator>Yoshida, Shintaro</creator><creator>Yagishita, Akira</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20161209</creationdate><title>Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser</title><author>Minemoto, Shinichirou ; Teramoto, Takahiro ; Akagi, Hiroshi ; Fujikawa, Takashi ; Majima, Takuya ; Nakajima, Kyo ; Niki, Kaori ; Owada, Shigeki ; Sakai, Hirofumi ; Togashi, Tadashi ; Tono, Kensuke ; Tsuru, Shota ; Wada, Ken ; Yabashi, Makina ; Yoshida, Shintaro ; Yagishita, Akira</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c548t-45cb5f04130685f2baa6693c503fc4632eebf00550a3172b8535160fd73ec2243</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>639/638/440/94</topic><topic>639/766/36/1121</topic><topic>Chemical reactions</topic><topic>Diffraction</topic><topic>Humanities and Social Sciences</topic><topic>Lasers</topic><topic>multidisciplinary</topic><topic>Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Minemoto, Shinichirou</creatorcontrib><creatorcontrib>Teramoto, Takahiro</creatorcontrib><creatorcontrib>Akagi, Hiroshi</creatorcontrib><creatorcontrib>Fujikawa, Takashi</creatorcontrib><creatorcontrib>Majima, Takuya</creatorcontrib><creatorcontrib>Nakajima, Kyo</creatorcontrib><creatorcontrib>Niki, Kaori</creatorcontrib><creatorcontrib>Owada, Shigeki</creatorcontrib><creatorcontrib>Sakai, Hirofumi</creatorcontrib><creatorcontrib>Togashi, Tadashi</creatorcontrib><creatorcontrib>Tono, Kensuke</creatorcontrib><creatorcontrib>Tsuru, Shota</creatorcontrib><creatorcontrib>Wada, Ken</creatorcontrib><creatorcontrib>Yabashi, Makina</creatorcontrib><creatorcontrib>Yoshida, Shintaro</creatorcontrib><creatorcontrib>Yagishita, Akira</creatorcontrib><collection>SpringerOpen</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health Medical collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>ProQuest Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection (Proquest) (PQ_SDU_P3)</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>PML(ProQuest Medical Library)</collection><collection>ProQuest Science Journals</collection><collection>ProQuest Biological Science Journals</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Minemoto, Shinichirou</au><au>Teramoto, Takahiro</au><au>Akagi, Hiroshi</au><au>Fujikawa, Takashi</au><au>Majima, Takuya</au><au>Nakajima, Kyo</au><au>Niki, Kaori</au><au>Owada, Shigeki</au><au>Sakai, Hirofumi</au><au>Togashi, Tadashi</au><au>Tono, Kensuke</au><au>Tsuru, Shota</au><au>Wada, Ken</au><au>Yabashi, Makina</au><au>Yoshida, Shintaro</au><au>Yagishita, Akira</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2016-12-09</date><risdate>2016</risdate><volume>6</volume><issue>1</issue><spage>38654</spage><epage>38654</epage><pages>38654-38654</pages><artnum>38654</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>We have successfully determined the internuclear distance of I
2
molecules in an alignment laser field by applying our molecular structure determination methodology to an I 2
p
X-ray photoelectron diffraction profile observed with femtosecond X-ray free electron laser pulses. Using this methodology, we have found that the internuclear distance of the sample I
2
molecules in an alignment Nd:YAG laser field of 6 × 10
11
W/cm
2
is elongated by from 0.18 to 0.30 Å “in average” relatively to the equilibrium internuclear distance of 2.666 Å. Thus, the present experiment constitutes a critical step towards the goal of femtosecond imaging of chemical reactions and opens a new direction for the study of ultrafast chemical reaction in the gas phase.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>27934891</pmid><doi>10.1038/srep38654</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 639/638/440/94 639/766/36/1121 Chemical reactions Diffraction Humanities and Social Sciences Lasers multidisciplinary Science |
| title | Structure determination of molecules in an alignment laser field by femtosecond photoelectron diffraction using an X-ray free-electron laser |
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