Manganese(I)-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination

Manganese‐catalyzed C−H bond activation chemistry is emerging as a powerful and complementary method for molecular functionalization. A highly reactive seven‐membered MnI intermediate is detected and characterized that is effective for H‐transfer or reductive elimination to deliver alkenylated or py...

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Veröffentlicht in:	Angewandte Chemie International Edition 2016-09, Vol.55 (40), p.12455-12459
Hauptverfasser:	Yahaya, Nasiru P., Appleby, Kate M., Teh, Magdalene, Wagner, Conrad, Troschke, Erik, Bray, Joshua T. W., Duckett, Simon B., Hammarback, L. Anders, Ward, Jonathan S., Milani, Jessica, Pridmore, Natalie E., Whitwood, Adrian C., Lynam, Jason M., Fairlamb, Ian J. S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation catalysis Communication Communications C−H activation functionalization Hydrogen bonds Manganese Pyridinium sustainability
Online-Zugang:	Volltext
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