Access to a new class of synthetic building blocks via trifluoromethoxylation of pyridines and pyrimidines

Since the first synthesis of trifluoromethyl ethers in 1935, the trifluoromethoxy (OCF ) group has made a remarkable impact in medicinal, agrochemical, and materials science research. However, our inability to facilely incorporate the OCF group into molecules, especially heteroaromatics, has limited...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-01, Vol.7 (1), p.424-429
Hauptverfasser:	Feng, Pengju, Lee, Katarzyna N, Lee, Johnny W, Zhan, Chengbo, Ngai, Ming-Yu
Format:	Artikel
Sprache:	eng
Schlagworte:	Agricultural chemicals Chemistry Cross coupling Ethers Pathways Pyridines Pyrimidines Radicals Synthesis
Online-Zugang:	Volltext
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