Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives

The development of a gold(I)‐catalyzed sulfination of aryl boronic acids is described. This transformation proceeds through an unprecedented mechanism which exploits the reactivity of gold(I)–heteroatom bonds to form sulfinate anions. Further in situ elaboration of the sulfinate intermediates leads...

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Veröffentlicht in:	Angewandte Chemie International Edition 2014-04, Vol.53 (17), p.4404-4407
Hauptverfasser:	Johnson, Miles W., Bagley, Scott W., Mankad, Neal P., Bergman, Robert G., Mascitti, Vincent, Toste, F. Dean
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Aromatic compounds Boronic Acids - chemistry Catalysis Derivatives Drugs gold Gold - chemistry heterocycles Metalorganic compounds Molecular Structure Organometallic Compounds - chemistry Pharmaceutical industry structure elucidation sulfonamides Sulfonamides - chemical synthesis Sulfones Sulfones - chemical synthesis Synthesis synthetic methods Transformations X-Ray Diffraction X-rays
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