Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation

The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the f...

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Veröffentlicht in:	European journal of organic chemistry 2016-07, Vol.2016 (19), p.3171-3176
Hauptverfasser:	Dorel, Ruth, de Mendoza, Paula, Calleja, Pilar, Pascual, Sergio, González-Cantalapiedra, Esther, Cabello, Noemí, Echavarren, Antonio M.
Format:	Artikel
Sprache:	eng
Schlagworte:	Arylation Fullerenes Mass spectrometry Palladium Truxene
Online-Zugang:	Volltext
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