Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation
The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the f...
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| Veröffentlicht in: | European journal of organic chemistry 2016-07, Vol.2016 (19), p.3171-3176 |
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| container_issue | 19 |
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| container_title | European journal of organic chemistry |
| container_volume | 2016 |
| creator | Dorel, Ruth de Mendoza, Paula Calleja, Pilar Pascual, Sergio González-Cantalapiedra, Esther Cabello, Noemí Echavarren, Antonio M. |
| description | The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI‐MS.
Advanced crushed fullerene C60H24, synthesized by a sixfold palladium‐catalyzed intramolecular arylation, forms C60 fullerene by high‐power laser irradiation in LDI‐MS |
| doi_str_mv | 10.1002/ejoc.201600311 |
| format | Article |
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Advanced crushed fullerene C60H24, synthesized by a sixfold palladium‐catalyzed intramolecular arylation, forms C60 fullerene by high‐power laser irradiation in LDI‐MS</description><subject>Arylation</subject><subject>Fullerenes</subject><subject>Mass spectrometry</subject><subject>Palladium</subject><subject>Truxene</subject><issn>1434-193X</issn><issn>1099-0690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNqFkc1v1DAQxS0EomXhyhFF4sIlix1_JL4glajtgioKbCu4WY4zabx442In0PDX42rLqnDhNJbm957m-SH0nOAlwbh4DRtvlgUmAmNKyAN0SLCUORYSP0xvRllOJP16gJ7EuMEYSyHIY3RQlGXJMK0O0eV6HsYeoo2Z7zKd1WGKPbTZyeQcBBggqwVeFSwb--Cnqz5b25vOuzb7qJ3TrZ22ea1H7eZfSXQUZqdH64en6FGnXYRnd3OBLk-OL-pVfnZ--q4-OssNx4LkuuS4A9ANK4CXwKnpKAEhGAEjtOigkIQ3hjek5KyVTKfrtWGVbrgwnZR0gd7sfK-nZgutgWEM2qnrYLc6zMprq_7eDLZXV_6H4pjTIv3AAr26Mwj--wRxVFsbDaRoA_gpKlJRzklVCZLQl_-gGz-FIcVLFC4IxSVjiVruKBN8jAG6_TEEq9vG1G1jat9YEry4H2GP_6koAXIH_LQO5v_YqeP35_V983yntXGEm71Wh29KlLTk6suHU_X5k3i7uii4WtPf0aWx7Q</recordid><startdate>201607</startdate><enddate>201607</enddate><creator>Dorel, Ruth</creator><creator>de Mendoza, Paula</creator><creator>Calleja, Pilar</creator><creator>Pascual, Sergio</creator><creator>González-Cantalapiedra, Esther</creator><creator>Cabello, Noemí</creator><creator>Echavarren, Antonio M.</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><general>John Wiley and Sons Inc</general><scope>BSCLL</scope><scope>24P</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-6808-3007</orcidid></search><sort><creationdate>201607</creationdate><title>Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation</title><author>Dorel, Ruth ; de Mendoza, Paula ; Calleja, Pilar ; Pascual, Sergio ; González-Cantalapiedra, Esther ; Cabello, Noemí ; Echavarren, Antonio M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5061-a750feeab42e57e53cf31e6641ec6a6fe2915bc5b1754d94a661ac48ab56cf993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Arylation</topic><topic>Fullerenes</topic><topic>Mass spectrometry</topic><topic>Palladium</topic><topic>Truxene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dorel, Ruth</creatorcontrib><creatorcontrib>de Mendoza, Paula</creatorcontrib><creatorcontrib>Calleja, Pilar</creatorcontrib><creatorcontrib>Pascual, Sergio</creatorcontrib><creatorcontrib>González-Cantalapiedra, Esther</creatorcontrib><creatorcontrib>Cabello, Noemí</creatorcontrib><creatorcontrib>Echavarren, Antonio M.</creatorcontrib><collection>Istex</collection><collection>Wiley Online Library Open Access</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>European journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dorel, Ruth</au><au>de Mendoza, Paula</au><au>Calleja, Pilar</au><au>Pascual, Sergio</au><au>González-Cantalapiedra, Esther</au><au>Cabello, Noemí</au><au>Echavarren, Antonio M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation</atitle><jtitle>European journal of organic chemistry</jtitle><addtitle>Eur. J. Org. Chem</addtitle><date>2016-07</date><risdate>2016</risdate><volume>2016</volume><issue>19</issue><spage>3171</spage><epage>3176</epage><pages>3171-3176</pages><issn>1434-193X</issn><eissn>1099-0690</eissn><abstract>The synthesis of a new C3v‐symmetric crushed fullerene C60H24 (5) has been accomplished in three steps from truxene through sixfold palladium‐catalyzed intramolecular arylation of a syn‐trialkylated truxene precursor. Laser irradiation of 5 induces cyclodehydrogenation processes that result in the formation of C60, as detected by LDI‐MS.
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| ispartof | European journal of organic chemistry, 2016-07, Vol.2016 (19), p.3171-3176 |
| issn | 1434-193X 1099-0690 |
| language | eng |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Arylation Fullerenes Mass spectrometry Palladium Truxene |
| title | Synthesis of a Crushed Fullerene C60H24 through Sixfold Palladium-Catalyzed Arylation |
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