Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons
Contributing to the need for new graphene nanoribbon (GNR) structures that can be synthesized with atomic precision, we have designed a reactant that renders chiral (3,1)-GNRs after a multistep reaction including Ullmann coupling and cyclodehydrogenation. The nanoribbon synthesis has been successful...
Gespeichert in:
| Veröffentlicht in: | ACS nano 2016-09, Vol.10 (9), p.9000-9008 |
|---|---|
| Hauptverfasser: | , , , , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 9008 |
|---|---|
| container_issue | 9 |
| container_start_page | 9000 |
| container_title | ACS nano |
| container_volume | 10 |
| creator | de Oteyza, Dimas G García-Lekue, Aran Vilas-Varela, Manuel Merino-Díez, Néstor Carbonell-Sanromà, Eduard Corso, Martina Vasseur, Guillaume Rogero, Celia Guitián, Enrique Pascual, Jose Ignacio Ortega, J. Enrique Wakayama, Yutaka Peña, Diego |
| description | Contributing to the need for new graphene nanoribbon (GNR) structures that can be synthesized with atomic precision, we have designed a reactant that renders chiral (3,1)-GNRs after a multistep reaction including Ullmann coupling and cyclodehydrogenation. The nanoribbon synthesis has been successfully proven on different coinage metals, and the formation process, together with the fingerprints associated with each reaction step, has been studied by combining scanning tunneling microscopy, core-level spectroscopy, and density functional calculations. In addition to the GNR’s chiral edge structure, the substantial GNR lengths achieved and the low processing temperature required to complete the reaction grant this reactant extremely interesting properties for potential applications. |
| doi_str_mv | 10.1021/acsnano.6b05269 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5043421</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1824224929</sourcerecordid><originalsourceid>FETCH-LOGICAL-a495t-be7acf1f99ec4298a37e8910a05834efd7a77fce62fe464a2d5014198749533</originalsourceid><addsrcrecordid>eNp1kcFLwzAYxYMobk7P3qRHQbolado0F2EMnYOhwjx4C2n21XV0yUxaZf-9kdWhBy9JSH7v5fE9hC4JHhJMyUhpb5Sxw6zAKc3EEeoTkWQxzrPX48M5JT105v0a45TnPDtFPcpTFq6zPnpctIVvnGognpklbCEspommzn42q8iW0bixm0qrut5Fzw505SGarCqn6sCo7QoMRI8hgauKwhp_jk5KVXu46PYBWtzfvUwe4vnTdDYZz2PFRNrEBXClS1IKAZpRkauEQy4IVjjNEwblkivOSw0ZLYFlTNFligkjIudBniQDdLt33bbFBpY6JA6B5NZVG-V20qpK_n0x1Uq-2Q-ZYpYwSoLBdWfg7HsLvpGbymuoa2XAtl6SnDJKmaAioKM9qp313kF5-IZg-d2B7DqQXQdBcfU73YH_GXoAbvZAUMq1bZ0Jo_rX7gu1wJRU</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1824224929</pqid></control><display><type>article</type><title>Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons</title><source>ACS Publications</source><creator>de Oteyza, Dimas G ; García-Lekue, Aran ; Vilas-Varela, Manuel ; Merino-Díez, Néstor ; Carbonell-Sanromà, Eduard ; Corso, Martina ; Vasseur, Guillaume ; Rogero, Celia ; Guitián, Enrique ; Pascual, Jose Ignacio ; Ortega, J. Enrique ; Wakayama, Yutaka ; Peña, Diego</creator><creatorcontrib>de Oteyza, Dimas G ; García-Lekue, Aran ; Vilas-Varela, Manuel ; Merino-Díez, Néstor ; Carbonell-Sanromà, Eduard ; Corso, Martina ; Vasseur, Guillaume ; Rogero, Celia ; Guitián, Enrique ; Pascual, Jose Ignacio ; Ortega, J. Enrique ; Wakayama, Yutaka ; Peña, Diego</creatorcontrib><description>Contributing to the need for new graphene nanoribbon (GNR) structures that can be synthesized with atomic precision, we have designed a reactant that renders chiral (3,1)-GNRs after a multistep reaction including Ullmann coupling and cyclodehydrogenation. The nanoribbon synthesis has been successfully proven on different coinage metals, and the formation process, together with the fingerprints associated with each reaction step, has been studied by combining scanning tunneling microscopy, core-level spectroscopy, and density functional calculations. In addition to the GNR’s chiral edge structure, the substantial GNR lengths achieved and the low processing temperature required to complete the reaction grant this reactant extremely interesting properties for potential applications.</description><identifier>ISSN: 1936-0851</identifier><identifier>EISSN: 1936-086X</identifier><identifier>DOI: 10.1021/acsnano.6b05269</identifier><identifier>PMID: 27548516</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><ispartof>ACS nano, 2016-09, Vol.10 (9), p.9000-9008</ispartof><rights>Copyright © 2016 American Chemical Society</rights><rights>Copyright © 2016 American Chemical Society 2016 American Chemical Society</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a495t-be7acf1f99ec4298a37e8910a05834efd7a77fce62fe464a2d5014198749533</citedby><cites>FETCH-LOGICAL-a495t-be7acf1f99ec4298a37e8910a05834efd7a77fce62fe464a2d5014198749533</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/acsnano.6b05269$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/acsnano.6b05269$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27548516$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>de Oteyza, Dimas G</creatorcontrib><creatorcontrib>García-Lekue, Aran</creatorcontrib><creatorcontrib>Vilas-Varela, Manuel</creatorcontrib><creatorcontrib>Merino-Díez, Néstor</creatorcontrib><creatorcontrib>Carbonell-Sanromà, Eduard</creatorcontrib><creatorcontrib>Corso, Martina</creatorcontrib><creatorcontrib>Vasseur, Guillaume</creatorcontrib><creatorcontrib>Rogero, Celia</creatorcontrib><creatorcontrib>Guitián, Enrique</creatorcontrib><creatorcontrib>Pascual, Jose Ignacio</creatorcontrib><creatorcontrib>Ortega, J. Enrique</creatorcontrib><creatorcontrib>Wakayama, Yutaka</creatorcontrib><creatorcontrib>Peña, Diego</creatorcontrib><title>Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons</title><title>ACS nano</title><addtitle>ACS Nano</addtitle><description>Contributing to the need for new graphene nanoribbon (GNR) structures that can be synthesized with atomic precision, we have designed a reactant that renders chiral (3,1)-GNRs after a multistep reaction including Ullmann coupling and cyclodehydrogenation. The nanoribbon synthesis has been successfully proven on different coinage metals, and the formation process, together with the fingerprints associated with each reaction step, has been studied by combining scanning tunneling microscopy, core-level spectroscopy, and density functional calculations. In addition to the GNR’s chiral edge structure, the substantial GNR lengths achieved and the low processing temperature required to complete the reaction grant this reactant extremely interesting properties for potential applications.</description><issn>1936-0851</issn><issn>1936-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kcFLwzAYxYMobk7P3qRHQbolado0F2EMnYOhwjx4C2n21XV0yUxaZf-9kdWhBy9JSH7v5fE9hC4JHhJMyUhpb5Sxw6zAKc3EEeoTkWQxzrPX48M5JT105v0a45TnPDtFPcpTFq6zPnpctIVvnGognpklbCEspommzn42q8iW0bixm0qrut5Fzw505SGarCqn6sCo7QoMRI8hgauKwhp_jk5KVXu46PYBWtzfvUwe4vnTdDYZz2PFRNrEBXClS1IKAZpRkauEQy4IVjjNEwblkivOSw0ZLYFlTNFligkjIudBniQDdLt33bbFBpY6JA6B5NZVG-V20qpK_n0x1Uq-2Q-ZYpYwSoLBdWfg7HsLvpGbymuoa2XAtl6SnDJKmaAioKM9qp313kF5-IZg-d2B7DqQXQdBcfU73YH_GXoAbvZAUMq1bZ0Jo_rX7gu1wJRU</recordid><startdate>20160927</startdate><enddate>20160927</enddate><creator>de Oteyza, Dimas G</creator><creator>García-Lekue, Aran</creator><creator>Vilas-Varela, Manuel</creator><creator>Merino-Díez, Néstor</creator><creator>Carbonell-Sanromà, Eduard</creator><creator>Corso, Martina</creator><creator>Vasseur, Guillaume</creator><creator>Rogero, Celia</creator><creator>Guitián, Enrique</creator><creator>Pascual, Jose Ignacio</creator><creator>Ortega, J. Enrique</creator><creator>Wakayama, Yutaka</creator><creator>Peña, Diego</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20160927</creationdate><title>Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons</title><author>de Oteyza, Dimas G ; García-Lekue, Aran ; Vilas-Varela, Manuel ; Merino-Díez, Néstor ; Carbonell-Sanromà, Eduard ; Corso, Martina ; Vasseur, Guillaume ; Rogero, Celia ; Guitián, Enrique ; Pascual, Jose Ignacio ; Ortega, J. Enrique ; Wakayama, Yutaka ; Peña, Diego</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a495t-be7acf1f99ec4298a37e8910a05834efd7a77fce62fe464a2d5014198749533</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>de Oteyza, Dimas G</creatorcontrib><creatorcontrib>García-Lekue, Aran</creatorcontrib><creatorcontrib>Vilas-Varela, Manuel</creatorcontrib><creatorcontrib>Merino-Díez, Néstor</creatorcontrib><creatorcontrib>Carbonell-Sanromà, Eduard</creatorcontrib><creatorcontrib>Corso, Martina</creatorcontrib><creatorcontrib>Vasseur, Guillaume</creatorcontrib><creatorcontrib>Rogero, Celia</creatorcontrib><creatorcontrib>Guitián, Enrique</creatorcontrib><creatorcontrib>Pascual, Jose Ignacio</creatorcontrib><creatorcontrib>Ortega, J. Enrique</creatorcontrib><creatorcontrib>Wakayama, Yutaka</creatorcontrib><creatorcontrib>Peña, Diego</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>ACS nano</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>de Oteyza, Dimas G</au><au>García-Lekue, Aran</au><au>Vilas-Varela, Manuel</au><au>Merino-Díez, Néstor</au><au>Carbonell-Sanromà, Eduard</au><au>Corso, Martina</au><au>Vasseur, Guillaume</au><au>Rogero, Celia</au><au>Guitián, Enrique</au><au>Pascual, Jose Ignacio</au><au>Ortega, J. Enrique</au><au>Wakayama, Yutaka</au><au>Peña, Diego</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons</atitle><jtitle>ACS nano</jtitle><addtitle>ACS Nano</addtitle><date>2016-09-27</date><risdate>2016</risdate><volume>10</volume><issue>9</issue><spage>9000</spage><epage>9008</epage><pages>9000-9008</pages><issn>1936-0851</issn><eissn>1936-086X</eissn><abstract>Contributing to the need for new graphene nanoribbon (GNR) structures that can be synthesized with atomic precision, we have designed a reactant that renders chiral (3,1)-GNRs after a multistep reaction including Ullmann coupling and cyclodehydrogenation. The nanoribbon synthesis has been successfully proven on different coinage metals, and the formation process, together with the fingerprints associated with each reaction step, has been studied by combining scanning tunneling microscopy, core-level spectroscopy, and density functional calculations. In addition to the GNR’s chiral edge structure, the substantial GNR lengths achieved and the low processing temperature required to complete the reaction grant this reactant extremely interesting properties for potential applications.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>27548516</pmid><doi>10.1021/acsnano.6b05269</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1936-0851 |
| ispartof | ACS nano, 2016-09, Vol.10 (9), p.9000-9008 |
| issn | 1936-0851 1936-086X |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5043421 |
| source | ACS Publications |
| title | Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-19T21%3A13%3A43IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Substrate-Independent%20Growth%20of%20Atomically%20Precise%20Chiral%20Graphene%20Nanoribbons&rft.jtitle=ACS%20nano&rft.au=de%20Oteyza,%20Dimas%20G&rft.date=2016-09-27&rft.volume=10&rft.issue=9&rft.spage=9000&rft.epage=9008&rft.pages=9000-9008&rft.issn=1936-0851&rft.eissn=1936-086X&rft_id=info:doi/10.1021/acsnano.6b05269&rft_dat=%3Cproquest_pubme%3E1824224929%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1824224929&rft_id=info:pmid/27548516&rfr_iscdi=true |