Dirhodium-catalyzed C-H arene amination using hydroxylamines

Primary and N-alkyl arylamine motifs are key functional groups in Pharmaceuticals, agrochemicals, and functional materials, as well as in bioactive natural products. However, there is a dearth of generally applicable methods for the direct replacement of aryl hydrogens with NH₂/NH(alkyl) moieties. H...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2016-09, Vol.353 (6304), p.1144-1147
Hauptverfasser:	Paudyal, Mahesh P., Adebesin, Adeniyi Michael, Burt, Scott R., Ess, Daniel H., Ma, Zhiwei, Kürti, László, Falck, John R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ambient temperature Amines Aromatic compounds Bonding agents Bonding strength Conversion Hydrogen Methods Organic compounds Pharmaceuticals Synthesis
Online-Zugang:	Volltext
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