Rh-Catalyzed Intermolecular Reactions of α‑Alkyl-α-Diazo Carbonyl Compounds with Selectivity over β‑Hydride Migration

Rh-carbenes derived from α-diazocarbonyl compounds have found broad utility across a remarkable range of reactivity, including cyclopropanation, cyclopropenation, C–H insertions, heteroatom–hydrogen insertions, and ylide forming reactions. However, in contrast to α-aryl or α-vinyl-α-diazocarbonyl co...

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Veröffentlicht in:	Accounts of chemical research 2016-01, Vol.49 (1), p.115-127
Hauptverfasser:	DeAngelis, Andrew, Panish, Robert, Fox, Joseph M
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemical synthesis Alkenes - chemistry Catalysis Cyclization Diazonium Compounds - chemistry Hydrogen - chemistry Methane - analogs & derivatives Methane - chemistry Molecular Structure Organometallic Compounds - chemistry Rhodium - chemistry Stereoisomerism
Online-Zugang:	Volltext
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