Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol
The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Elect...
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| Veröffentlicht in: | Scientific reports 2016-06, Vol.6 (1), p.27328-27328, Article 27328 |
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| description | The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Electrical Impedance Spectroscopy. The highest conductivity achieved is 1.64 × 10
−4
S cm
−1
for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor. |
| doi_str_mv | 10.1038/srep27328 |
| format | Article |
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−4
S cm
−1
for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep27328</identifier><identifier>PMID: 27265642</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301 ; 639/766/119/995 ; Acids ; Biodegradable materials ; Biopolymers ; Biopolymers - chemistry ; Carboxymethylcellulose Sodium - metabolism ; Cellulose ; Conductivity ; Diffusion coefficient ; Electric Conductivity ; Electrodes ; Electrolytes ; Fourier transforms ; Glycerol ; Glycerol - metabolism ; Humanities and Social Sciences ; multidisciplinary ; Oleic Acid - metabolism ; Polymers ; Protons ; Science ; Spectrum analysis</subject><ispartof>Scientific reports, 2016-06, Vol.6 (1), p.27328-27328, Article 27328</ispartof><rights>The Author(s) 2016</rights><rights>Copyright Nature Publishing Group Jun 2016</rights><rights>Copyright © 2016, Macmillan Publishers Limited 2016 Macmillan Publishers Limited</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c438t-3e779883567a8b1b8ab80489bdfb5d6d2784d424d55fe78e3de882ae292020643</citedby><cites>FETCH-LOGICAL-c438t-3e779883567a8b1b8ab80489bdfb5d6d2784d424d55fe78e3de882ae292020643</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4893606/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4893606/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,41120,42189,51576,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27265642$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Chai, M. N.</creatorcontrib><creatorcontrib>Isa, M. I. N.</creatorcontrib><title>Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Electrical Impedance Spectroscopy. The highest conductivity achieved is 1.64 × 10
−4
S cm
−1
for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor.</description><subject>639/301</subject><subject>639/766/119/995</subject><subject>Acids</subject><subject>Biodegradable materials</subject><subject>Biopolymers</subject><subject>Biopolymers - chemistry</subject><subject>Carboxymethylcellulose Sodium - metabolism</subject><subject>Cellulose</subject><subject>Conductivity</subject><subject>Diffusion coefficient</subject><subject>Electric Conductivity</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Fourier transforms</subject><subject>Glycerol</subject><subject>Glycerol - metabolism</subject><subject>Humanities and Social Sciences</subject><subject>multidisciplinary</subject><subject>Oleic Acid - metabolism</subject><subject>Polymers</subject><subject>Protons</subject><subject>Science</subject><subject>Spectrum analysis</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>EIF</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNplkdFuFCEUhidGY5vaC1_AkHijJmMZYIC5MWnXWk0a20S9Jgyc3aVhhxGYtusr-NJSt92slRs4-T_-c07-qnrZ4PcNpvIoRRiJoEQ-qfYJZm1NKCFPd9571WFKV7iclnSs6Z5Xe0QQ3nJG9qvfX8M1eHQZQw4DmoXBTia7YYG-Be8sOnGhHoNfryCiUw8mx1JkSOhEJ7Do7ouOfbgtQF6uPZqB95MPCdDHMBbgxuUluvDgDDo2xU8PFl16nbIz7teDfubXBorxi-rZXPsEh_f3QfXj0-n32ef6_OLsy-z4vDaMylxTEKKTkrZcaNk3vdS9xEx2vZ33reWWCMksI8y27RyEBGpBSqKBdAQTzBk9qD5sfMepX4E1MOSovRqjW-m4VkE79a8yuKVahGtVmlCOeTF4c28Qw88JUlYrl0xZXQ8QpqQa0THGpeBNQV8_Qq_CFIey3l-qoZhzWai3G8rEkEqg8-0wDVZ3KattyoV9tTv9lnzItADvNkAq0rCAuNPyP7c_E6OzFw</recordid><startdate>20160606</startdate><enddate>20160606</enddate><creator>Chai, M. 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N.</au><au>Isa, M. I. N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2016-06-06</date><risdate>2016</risdate><volume>6</volume><issue>1</issue><spage>27328</spage><epage>27328</epage><pages>27328-27328</pages><artnum>27328</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>The plasticized solid bio-polymer electrolytes (SBEs) system has been formed by introducing glycerol (Gly) as the plasticizer into the carboxymethyl cellulose (CMC) doped with oleic acid (OA) via solution casting techniques. The ionic conductivity of the plasticized SBEs has been studied using Electrical Impedance Spectroscopy. The highest conductivity achieved is 1.64 × 10
−4
S cm
−1
for system containing 40 wt. % of glycerol. FTIR deconvolution technique had shown that the conductivity of CMC-OA-Gly SBEs is primarily influenced by the number density of mobile ions. Transference number measurement has shown that the cation diffusion coefficient and ionic mobility is higher than anion which proved the plasticized polymer system is a proton conductor.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>27265642</pmid><doi>10.1038/srep27328</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 639/301 639/766/119/995 Acids Biodegradable materials Biopolymers Biopolymers - chemistry Carboxymethylcellulose Sodium - metabolism Cellulose Conductivity Diffusion coefficient Electric Conductivity Electrodes Electrolytes Fourier transforms Glycerol Glycerol - metabolism Humanities and Social Sciences multidisciplinary Oleic Acid - metabolism Polymers Protons Science Spectrum analysis |
| title | Novel Proton Conducting Solid Bio-polymer Electrolytes Based on Carboxymethyl Cellulose Doped with Oleic Acid and Plasticized with Glycerol |
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