Stepwise Polychlorination of 8‑Chloro-BODIPY and Regioselective Functionalization of 2,3,5,6,8-Pentachloro-BODIPY

An effective, stepwise methodology for polychlorination of BODIPY using trichloroisocyanuric acid (TCCA) in acetic acid was developed. In this way, selectively substituted di-, tri-, tetra-, and pentachloro-BODIPYs 2–5 were prepared. The pentachloro-BODIPY is shown to undergo regioselective Pd(0)-ca...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2015-08, Vol.80 (16), p.8377-8383
Hauptverfasser:	Zhao, Ning, Xuan, Sunting, Fronczek, Frank R, Smith, Kevin M, Vicente, M. Graça H
Format:	Artikel
Sprache:	eng
Schlagworte:	acetic acid Aza Compounds - chemistry Boron Compounds - chemistry Catalysis chemical reactions chemical structure Crystallography, X-Ray Hydrocarbons, Chlorinated - chemical synthesis Hydrocarbons, Chlorinated - chemistry Hydrocarbons, Halogenated - chemistry Lewis bases Molecular Structure organic chemistry regioselectivity
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!