Kemp elimination in cationic micelles: designed enzyme-like rates achieved through the addition of long-chain bases

The Kemp elimination is prototypical reaction used to study proton ion from carbon. Several hydrophobic systems are known to accelerate this reaction, including two classes of computationally designed enzymes. However, it is unclear whether these computationally designed enzymes establish specific i...

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Veröffentlicht in:	Journal of physical organic chemistry 2016-04, Vol.29 (4), p.185-189
Hauptverfasser:	Sanchez, Enis, Lu, Saoran, Reed, Carson, Schmidt, Joshua, Forconi, Marcello
Format:	Artikel
Sprache:	eng
Schlagworte:	catalysis enzyme design hydrophobic interactions Kemp elimination micelles
Online-Zugang:	Volltext
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