Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis

One shortcoming of olefin metathesis has been that acyclic alkenyl halides could not be generated efficiently and stereoselectively; but now halo-substituted molybdenum alkylidene species are shown to be able to participate in high-yielding olefin metathesis reactions that afford acyclic 1,2-disubst...

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Veröffentlicht in:	Nature (London) 2016-03, Vol.531 (7595), p.459-465
Hauptverfasser:	Koh, Ming Joo, Nguyen, Thach T., Zhang, Hanmo, Schrock, Richard R., Hoveyda, Amir H.
Format:	Artikel
Sprache:	eng
Schlagworte:	140/131 140/146 639/638/403 639/638/77 Alkenes - chemical synthesis Alkenes - chemistry Ambient temperature Biological Products - chemical synthesis Biological Products - chemistry Bromides Bromides - chemical synthesis Bromides - chemistry Catalysis Catalysts Chemical properties Chemical synthesis Chlorides - chemical synthesis Chlorides - chemistry Fluorides Fluorides - chemical synthesis Fluorides - chemistry Halides Halogenation Humanities and Social Sciences Identification and classification Methods Molybdenum Molybdenum - chemistry multidisciplinary Observations Olefins Organic chemistry Production processes Reagents Ruthenium Science Structure
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