Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al
Mn 2 O 3 has been selected to realize nanothermite membrane for the first time in the literature. Mn 2 O 3 /Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn 2 O 3 skeleton. The energy release is significantly enhan...
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| Veröffentlicht in: | Scientific reports 2016-03, Vol.6 (1), p.22588-22588, Article 22588 |
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| creator | Zheng, Guoqiang Zhang, Wenchao Shen, Ruiqi Ye, Jiahai Qin, Zhichun Chao, Yimin |
| description | Mn
2
O
3
has been selected to realize nanothermite membrane for the first time in the literature. Mn
2
O
3
/Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn
2
O
3
skeleton. The energy release is significantly enhanced owing to the unusual 3DOM structure, which ensures Al and Mn
2
O
3
to integrate compactly in nanoscale and greatly increase effective contact area. The morphology and DSC curve of the nanothermite membrane have been investigated at various aluminizing times. At the optimized aluminizing time of 30 min, energy release reaches a maximum of 2.09 kJ∙g
−1
, where the Al layer thickness plays a decisive role in the total energy release. This method possesses advantages of high compatibility with MEMS and can be applied to other nanothermite systems easily, which will make great contribution to little-known nanothermite research. |
| doi_str_mv | 10.1038/srep22588 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4776280</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>4147141761</sourcerecordid><originalsourceid>FETCH-LOGICAL-c438t-73bf8916ae48bfc514c26d9fa7b55e90c3e6b3c62ec54b4f34fc55df230a189f3</originalsourceid><addsrcrecordid>eNplkc1LHDEYxkOxqNg9-A-UAS9amG4-Z5KLsIi1Bbd7qJ48hEzmjTsyk6zJTMH_vimry9rm8gaeH8_78SB0SvBXgpmcpwgbSoWUH9AxxVyUlFF6sPc_QrOUnnB-gipO1CE6opVigmNxjB7u1hGgbLsBfOqCN33_UqxiCxHaYmlsDJsQw5SKX2Oc7DhFKK69afqs_jQ-jGuIQzdCsYShicZDEVyx9HTF5ov-E_roTJ9g9lpP0P2367ur7-Xt6ubH1eK2tJzJsaxZ46QilQEuG2cF4ZZWrXKmboQAhS2DqmG2omAFb7hjPEOidZRhQ6Ry7ARdbn03UzNAa8GP0fR6E7vBxBcdTKffK75b68fwW_O6rqjE2eD81SCG5wnSqIcuWej7vFDeXZO6xrISkqiMnv2DPoUp5rNlShJCpVI1y9TFlsr3SzkgtxuGYP03Nb1LLbOf96ffkW8ZZeDLFkhZ8o8Q91r-5_YHrPKiKg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1811289973</pqid></control><display><type>article</type><title>Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al</title><source>DOAJ Directory of Open Access Journals</source><source>Springer Nature OA Free Journals</source><source>Nature Free</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Zheng, Guoqiang ; Zhang, Wenchao ; Shen, Ruiqi ; Ye, Jiahai ; Qin, Zhichun ; Chao, Yimin</creator><creatorcontrib>Zheng, Guoqiang ; Zhang, Wenchao ; Shen, Ruiqi ; Ye, Jiahai ; Qin, Zhichun ; Chao, Yimin</creatorcontrib><description>Mn
2
O
3
has been selected to realize nanothermite membrane for the first time in the literature. Mn
2
O
3
/Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn
2
O
3
skeleton. The energy release is significantly enhanced owing to the unusual 3DOM structure, which ensures Al and Mn
2
O
3
to integrate compactly in nanoscale and greatly increase effective contact area. The morphology and DSC curve of the nanothermite membrane have been investigated at various aluminizing times. At the optimized aluminizing time of 30 min, energy release reaches a maximum of 2.09 kJ∙g
−1
, where the Al layer thickness plays a decisive role in the total energy release. This method possesses advantages of high compatibility with MEMS and can be applied to other nanothermite systems easily, which will make great contribution to little-known nanothermite research.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep22588</identifier><identifier>PMID: 26935405</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/166/898 ; 639/301/1005 ; Energy ; Humanities and Social Sciences ; Investigations ; Manganese oxides ; Metal oxides ; Microelectromechanical systems ; Morphology ; multidisciplinary ; Nanoparticles ; Point defects ; Pore size ; Science ; Spheres</subject><ispartof>Scientific reports, 2016-03, Vol.6 (1), p.22588-22588, Article 22588</ispartof><rights>The Author(s) 2016</rights><rights>Copyright Nature Publishing Group Mar 2016</rights><rights>Copyright © 2016, Macmillan Publishers Limited 2016 Macmillan Publishers Limited</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c438t-73bf8916ae48bfc514c26d9fa7b55e90c3e6b3c62ec54b4f34fc55df230a189f3</citedby><cites>FETCH-LOGICAL-c438t-73bf8916ae48bfc514c26d9fa7b55e90c3e6b3c62ec54b4f34fc55df230a189f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4776280/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4776280/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,41120,42189,51576,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26935405$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Zheng, Guoqiang</creatorcontrib><creatorcontrib>Zhang, Wenchao</creatorcontrib><creatorcontrib>Shen, Ruiqi</creatorcontrib><creatorcontrib>Ye, Jiahai</creatorcontrib><creatorcontrib>Qin, Zhichun</creatorcontrib><creatorcontrib>Chao, Yimin</creatorcontrib><title>Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Mn
2
O
3
has been selected to realize nanothermite membrane for the first time in the literature. Mn
2
O
3
/Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn
2
O
3
skeleton. The energy release is significantly enhanced owing to the unusual 3DOM structure, which ensures Al and Mn
2
O
3
to integrate compactly in nanoscale and greatly increase effective contact area. The morphology and DSC curve of the nanothermite membrane have been investigated at various aluminizing times. At the optimized aluminizing time of 30 min, energy release reaches a maximum of 2.09 kJ∙g
−1
, where the Al layer thickness plays a decisive role in the total energy release. This method possesses advantages of high compatibility with MEMS and can be applied to other nanothermite systems easily, which will make great contribution to little-known nanothermite research.</description><subject>639/166/898</subject><subject>639/301/1005</subject><subject>Energy</subject><subject>Humanities and Social Sciences</subject><subject>Investigations</subject><subject>Manganese oxides</subject><subject>Metal oxides</subject><subject>Microelectromechanical systems</subject><subject>Morphology</subject><subject>multidisciplinary</subject><subject>Nanoparticles</subject><subject>Point defects</subject><subject>Pore size</subject><subject>Science</subject><subject>Spheres</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNplkc1LHDEYxkOxqNg9-A-UAS9amG4-Z5KLsIi1Bbd7qJ48hEzmjTsyk6zJTMH_vimry9rm8gaeH8_78SB0SvBXgpmcpwgbSoWUH9AxxVyUlFF6sPc_QrOUnnB-gipO1CE6opVigmNxjB7u1hGgbLsBfOqCN33_UqxiCxHaYmlsDJsQw5SKX2Oc7DhFKK69afqs_jQ-jGuIQzdCsYShicZDEVyx9HTF5ov-E_roTJ9g9lpP0P2367ur7-Xt6ubH1eK2tJzJsaxZ46QilQEuG2cF4ZZWrXKmboQAhS2DqmG2omAFb7hjPEOidZRhQ6Ry7ARdbn03UzNAa8GP0fR6E7vBxBcdTKffK75b68fwW_O6rqjE2eD81SCG5wnSqIcuWej7vFDeXZO6xrISkqiMnv2DPoUp5rNlShJCpVI1y9TFlsr3SzkgtxuGYP03Nb1LLbOf96ffkW8ZZeDLFkhZ8o8Q91r-5_YHrPKiKg</recordid><startdate>20160303</startdate><enddate>20160303</enddate><creator>Zheng, Guoqiang</creator><creator>Zhang, Wenchao</creator><creator>Shen, Ruiqi</creator><creator>Ye, Jiahai</creator><creator>Qin, Zhichun</creator><creator>Chao, Yimin</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20160303</creationdate><title>Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al</title><author>Zheng, Guoqiang ; Zhang, Wenchao ; Shen, Ruiqi ; Ye, Jiahai ; Qin, Zhichun ; Chao, Yimin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c438t-73bf8916ae48bfc514c26d9fa7b55e90c3e6b3c62ec54b4f34fc55df230a189f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>639/166/898</topic><topic>639/301/1005</topic><topic>Energy</topic><topic>Humanities and Social Sciences</topic><topic>Investigations</topic><topic>Manganese oxides</topic><topic>Metal oxides</topic><topic>Microelectromechanical systems</topic><topic>Morphology</topic><topic>multidisciplinary</topic><topic>Nanoparticles</topic><topic>Point defects</topic><topic>Pore size</topic><topic>Science</topic><topic>Spheres</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zheng, Guoqiang</creatorcontrib><creatorcontrib>Zhang, Wenchao</creatorcontrib><creatorcontrib>Shen, Ruiqi</creatorcontrib><creatorcontrib>Ye, Jiahai</creatorcontrib><creatorcontrib>Qin, Zhichun</creatorcontrib><creatorcontrib>Chao, Yimin</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zheng, Guoqiang</au><au>Zhang, Wenchao</au><au>Shen, Ruiqi</au><au>Ye, Jiahai</au><au>Qin, Zhichun</au><au>Chao, Yimin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2016-03-03</date><risdate>2016</risdate><volume>6</volume><issue>1</issue><spage>22588</spage><epage>22588</epage><pages>22588-22588</pages><artnum>22588</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Mn
2
O
3
has been selected to realize nanothermite membrane for the first time in the literature. Mn
2
O
3
/Al nanothermite has been synthesized by magnetron sputtering a layer of Al film onto three-dimensionally ordered macroporous (3DOM) Mn
2
O
3
skeleton. The energy release is significantly enhanced owing to the unusual 3DOM structure, which ensures Al and Mn
2
O
3
to integrate compactly in nanoscale and greatly increase effective contact area. The morphology and DSC curve of the nanothermite membrane have been investigated at various aluminizing times. At the optimized aluminizing time of 30 min, energy release reaches a maximum of 2.09 kJ∙g
−1
, where the Al layer thickness plays a decisive role in the total energy release. This method possesses advantages of high compatibility with MEMS and can be applied to other nanothermite systems easily, which will make great contribution to little-known nanothermite research.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>26935405</pmid><doi>10.1038/srep22588</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| source | DOAJ Directory of Open Access Journals; Springer Nature OA Free Journals; Nature Free; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | 639/166/898 639/301/1005 Energy Humanities and Social Sciences Investigations Manganese oxides Metal oxides Microelectromechanical systems Morphology multidisciplinary Nanoparticles Point defects Pore size Science Spheres |
| title | Three-dimensionally Ordered Macroporous Structure Enabled Nanothermite Membrane of Mn2O3/Al |
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