Development of Conductometric Sensor Based on 25,27-Di-(5-thio-octyloxy)calix[4]arene-crown-6 for Determination of Ammonium
The conductometric sensor based on 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 was developed for the quantitative analysis of ammonium. The calixarene was immobilized on the surface of the planar interdigitated electrodes by attachment of its dialkyl sulfide groups to the surface of the gold ele...
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| Veröffentlicht in: | Nanoscale research letters 2016-12, Vol.11 (1), p.105-105, Article 105 |
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| creator | Saiapina, O. Y. Kharchenko, S. G. Vishnevskii, S. G. Pyeshkova, V. M. Kalchenko, V. I. Dzyadevych, S. V. |
| description | The conductometric sensor based on 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 was developed for the quantitative analysis of ammonium. The calixarene was immobilized on the surface of the planar interdigitated electrodes by attachment of its dialkyl sulfide groups to the surface of the gold electrodes. The intrinsic ability of the calixarene to capture ammonium was studied in the conductometric measuring mode and by the electrochemical impedance spectroscopy. The developed sensor showed high selectivity to ammonium in the presence of mono-, di-, and trivalent cations. Selective and highly sensitive detection of ammonium resulted from the complexation between the ammonium ions and a crown-ether fragment of the upper rim of the 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 macrocycle. The developed sensor had high signal repeatability. Its sensitivity was found to be satisfactory for the forthcoming sensor application in the water-sample analysis; the linear range was 0.01–1.5 mM and limit of detection 10 μM. |
| doi_str_mv | 10.1186/s11671-016-1317-9 |
| format | Article |
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Y. ; Kharchenko, S. G. ; Vishnevskii, S. G. ; Pyeshkova, V. M. ; Kalchenko, V. I. ; Dzyadevych, S. V.</creator><creatorcontrib>Saiapina, O. Y. ; Kharchenko, S. G. ; Vishnevskii, S. G. ; Pyeshkova, V. M. ; Kalchenko, V. I. ; Dzyadevych, S. V.</creatorcontrib><description>The conductometric sensor based on 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 was developed for the quantitative analysis of ammonium. The calixarene was immobilized on the surface of the planar interdigitated electrodes by attachment of its dialkyl sulfide groups to the surface of the gold electrodes. The intrinsic ability of the calixarene to capture ammonium was studied in the conductometric measuring mode and by the electrochemical impedance spectroscopy. The developed sensor showed high selectivity to ammonium in the presence of mono-, di-, and trivalent cations. Selective and highly sensitive detection of ammonium resulted from the complexation between the ammonium ions and a crown-ether fragment of the upper rim of the 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 macrocycle. The developed sensor had high signal repeatability. Its sensitivity was found to be satisfactory for the forthcoming sensor application in the water-sample analysis; the linear range was 0.01–1.5 mM and limit of detection 10 μM.</description><identifier>ISSN: 1931-7573</identifier><identifier>EISSN: 1556-276X</identifier><identifier>DOI: 10.1186/s11671-016-1317-9</identifier><identifier>PMID: 26911569</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Attachment ; Calixarenes ; Chemistry and Materials Science ; Complexation ; Electrodes ; Materials Science ; Molecular Medicine ; Nano Express ; Nanochemistry ; Nanoscale Science and Technology ; Nanotechnology ; Nanotechnology and Microengineering ; Nanotechnology and Nanomaterials (NANO-2015) ; Quantitative analysis ; Reproducibility ; Sensors ; Sulfides</subject><ispartof>Nanoscale research letters, 2016-12, Vol.11 (1), p.105-105, Article 105</ispartof><rights>Saiapina et al. 2016</rights><rights>The Author(s) 2016</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c503t-470ae7074f6e45fd886bb0a110fc4bfc11ec1999397f6ccb98a12da794d67c3f3</citedby><cites>FETCH-LOGICAL-c503t-470ae7074f6e45fd886bb0a110fc4bfc11ec1999397f6ccb98a12da794d67c3f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4766146/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4766146/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,861,882,27905,27906,53772,53774</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26911569$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Saiapina, O. Y.</creatorcontrib><creatorcontrib>Kharchenko, S. G.</creatorcontrib><creatorcontrib>Vishnevskii, S. G.</creatorcontrib><creatorcontrib>Pyeshkova, V. M.</creatorcontrib><creatorcontrib>Kalchenko, V. I.</creatorcontrib><creatorcontrib>Dzyadevych, S. V.</creatorcontrib><title>Development of Conductometric Sensor Based on 25,27-Di-(5-thio-octyloxy)calix[4]arene-crown-6 for Determination of Ammonium</title><title>Nanoscale research letters</title><addtitle>Nanoscale Res Lett</addtitle><addtitle>Nanoscale Res Lett</addtitle><description>The conductometric sensor based on 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 was developed for the quantitative analysis of ammonium. The calixarene was immobilized on the surface of the planar interdigitated electrodes by attachment of its dialkyl sulfide groups to the surface of the gold electrodes. The intrinsic ability of the calixarene to capture ammonium was studied in the conductometric measuring mode and by the electrochemical impedance spectroscopy. The developed sensor showed high selectivity to ammonium in the presence of mono-, di-, and trivalent cations. Selective and highly sensitive detection of ammonium resulted from the complexation between the ammonium ions and a crown-ether fragment of the upper rim of the 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 macrocycle. The developed sensor had high signal repeatability. 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Y.</au><au>Kharchenko, S. G.</au><au>Vishnevskii, S. G.</au><au>Pyeshkova, V. M.</au><au>Kalchenko, V. I.</au><au>Dzyadevych, S. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Development of Conductometric Sensor Based on 25,27-Di-(5-thio-octyloxy)calix[4]arene-crown-6 for Determination of Ammonium</atitle><jtitle>Nanoscale research letters</jtitle><stitle>Nanoscale Res Lett</stitle><addtitle>Nanoscale Res Lett</addtitle><date>2016-12-01</date><risdate>2016</risdate><volume>11</volume><issue>1</issue><spage>105</spage><epage>105</epage><pages>105-105</pages><artnum>105</artnum><issn>1931-7573</issn><eissn>1556-276X</eissn><abstract>The conductometric sensor based on 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 was developed for the quantitative analysis of ammonium. The calixarene was immobilized on the surface of the planar interdigitated electrodes by attachment of its dialkyl sulfide groups to the surface of the gold electrodes. The intrinsic ability of the calixarene to capture ammonium was studied in the conductometric measuring mode and by the electrochemical impedance spectroscopy. The developed sensor showed high selectivity to ammonium in the presence of mono-, di-, and trivalent cations. Selective and highly sensitive detection of ammonium resulted from the complexation between the ammonium ions and a crown-ether fragment of the upper rim of the 25,27-di-(5-thio-octyloxy)calix[4]arene-crown-6 macrocycle. The developed sensor had high signal repeatability. Its sensitivity was found to be satisfactory for the forthcoming sensor application in the water-sample analysis; the linear range was 0.01–1.5 mM and limit of detection 10 μM.</abstract><cop>New York</cop><pub>Springer US</pub><pmid>26911569</pmid><doi>10.1186/s11671-016-1317-9</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Attachment Calixarenes Chemistry and Materials Science Complexation Electrodes Materials Science Molecular Medicine Nano Express Nanochemistry Nanoscale Science and Technology Nanotechnology Nanotechnology and Microengineering Nanotechnology and Nanomaterials (NANO-2015) Quantitative analysis Reproducibility Sensors Sulfides |
| title | Development of Conductometric Sensor Based on 25,27-Di-(5-thio-octyloxy)calix[4]arene-crown-6 for Determination of Ammonium |
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