Self-Growth of Centimeter-Scale Single Crystals by Normal Sintering Process in Modified Potassium Sodium Niobate Ceramics

In this manuscript, an interesting phenomenon is reported. That is the self-growth of single crystals in Pb-free piezoelectric ceramics. These crystals are several centimeters in size. They are grown without any seed addition through a normal sintering process in modified potassium sodium niobate ce...

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Veröffentlicht in:Scientific reports 2015-12, Vol.5 (1), p.17656-17656, Article 17656
Hauptverfasser: Ahn, Cheol-Woo, Lee, Ho-Yong, Han, Guifang, Zhang, Shujun, Choi, Si-Young, Choi, Jong-Jin, Kim, Jong-Woo, Yoon, Woon-Ha, Choi, Joon-Hwan, Park, Dong-Soo, Hahn, Byung-Dong, Ryu, Jungho
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container_title Scientific reports
container_volume 5
creator Ahn, Cheol-Woo
Lee, Ho-Yong
Han, Guifang
Zhang, Shujun
Choi, Si-Young
Choi, Jong-Jin
Kim, Jong-Woo
Yoon, Woon-Ha
Choi, Joon-Hwan
Park, Dong-Soo
Hahn, Byung-Dong
Ryu, Jungho
description In this manuscript, an interesting phenomenon is reported. That is the self-growth of single crystals in Pb-free piezoelectric ceramics. These crystals are several centimeters in size. They are grown without any seed addition through a normal sintering process in modified potassium sodium niobate ceramics. It has been achieved by the composition designed to compensate the Na + loss which occurs during the liquid phase sintering. The composition of the crystals is (K 0.4925 Na 0.4925−x Ba 0.015+x/2 )Nb 0.995+x O 3 [x is determined by the Na + loss, due to Na 2 O volatilization]. These crystals have high piezoelectric voltage coefficients (g 33 , 131 10 −3 Vm/N ), indicating that they are good candidates for piezoelectric sensors and energy harvesting devices. We hope that this report can offer the opportunity for many researchers to have an interest in these crystals.
doi_str_mv 10.1038/srep17656
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subjects 639/301/1005/1009
639/301/119/996
Ceramics
Crystals
Humanities and Social Sciences
multidisciplinary
Potassium
Science
Single crystals
Sintering
Sodium
Volatilization
title Self-Growth of Centimeter-Scale Single Crystals by Normal Sintering Process in Modified Potassium Sodium Niobate Ceramics
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