Highly Selective Synthesis of Halomon, Plocamenone, and Isoplocamenone

Over 160 chiral vicinal bromo­chlorinated natural products have been identified; however, a lack of synthetic methods for the selective incorporation of halogens into organic molecules has hindered their synthesis. Here we disclose the first total synthesis and structural confirmation of iso­plocam­...

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Veröffentlicht in:Journal of the American Chemical Society 2015-10, Vol.137 (40), p.12784-12787
Hauptverfasser: Bucher, Cyril, Deans, Richard M, Burns, Noah Z
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Sprache:eng
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