Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)

Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-(i)Pr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C-F or C-O bond to the Al(I) centre.

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (88), p.15994-15996
Hauptverfasser:	Crimmin, Mark R, Butler, Michael J, White, Andrew J P
Format:	Artikel
Sprache:	eng
Schlagworte:	aluminum Aluminum - chemistry Benzofurans - chemistry chemical bonding Chemical bonds chemical reactions Chemistry Fluorobenzenes - chemistry Fluorocarbons - chemistry Organometallic Compounds - chemical synthesis Oxidation-Reduction
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-(i)Pr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C-F or C-O bond to the Al(I) centre.
ISSN:	1359-7345 1364-548X 1364-548X
DOI:	10.1039/c5cc07140b