Direct Observation of Intermediates Involved in the Interruption of the Bischler–Napieralski Reaction

The first mechanistic investigation of electrophilic amide activation of α,α-disubstituted tertiary lactams and the direct observation of key intermediates by in situ FTIR, 1H, 13C, and 19F NMR in our interrupted Bischler–Napieralski-based synthetic strategy to the aspidosperma alkaloids, including...

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Veröffentlicht in:	Journal of organic chemistry 2015-08, Vol.80 (15), p.7403-7411
Hauptverfasser:	White, Kolby L, Mewald, Marius, Movassaghi, Mohammad
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkaloids - chemistry Amides - chemistry Aspidosperma - chemistry Fluorine Radioisotopes - chemistry Lactams - chemistry Magnetic Resonance Spectroscopy Mesylates - chemistry Molecular Structure Pyridinium Compounds - chemistry Spectroscopy, Fourier Transform Infrared
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