A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials
Three ZnAl 2 O 4 samples were prepared via a modified polyacrylamide gel method using a citric acid solution with different aluminum salt starting materials, including AlCl 3 ∙6H 2 O, Al 2 (SO 4 ) 3 ∙18H 2 O and Al(NO 3 ) 3 ∙9H 2 O under identical conditions. The influence of different aluminum salt...
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| Veröffentlicht in: | Scientific reports 2015-08, Vol.5 (1), p.12849-12849, Article 12849 |
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| creator | Wang, Shi-Fa Sun, Guang-Zhuang Fang, Lei-Ming Lei, Li Xiang, Xia Zu, Xiao-Tao |
| description | Three ZnAl
2
O
4
samples were prepared via a modified polyacrylamide gel method using a citric acid solution with different aluminum salt starting materials, including AlCl
3
∙6H
2
O, Al
2
(SO
4
)
3
∙18H
2
O and Al(NO
3
)
3
∙9H
2
O under identical conditions. The influence of different aluminum salts on the morphologies, phase purity and optical and fluorescence properties of the as-prepared ZnAl
2
O
4
nanoparticles were studied. The experimental results demonstrate that the phase purity, particle size, morphology and optical and fluorescence properties of ZnAl
2
O
4
nanoparticles can be manipulated by the use of different aluminum salts as starting materials. The energy bandgap (Eg) values of ZnAl
2
O
4
nanoparticles increase with a decrease in particle size. The fluorescence spectra show that a major blue emission band around 400 nm and two weaker side bands located at 410 and 445 nm are observed when the excitation wavelength is 325 nm. The ZnAl
2
O
4
nanoparticles prepared from Al(NO
3
)
3
∙9H
2
O exhibit the largest emission intensity among the three ZnAl
2
O
4
samples, followed in turn by the ZnAl
2
O
4
nanoparticles prepared from Al
2
(SO
4
)
3
∙18H
2
O and AlCl
3
∙6H
2
O. These differences are attributed to combinational changes in Eg and the defect types of the ZnAl
2
O
4
nanoparticles. |
| doi_str_mv | 10.1038/srep12849 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4523878</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1702090045</sourcerecordid><originalsourceid>FETCH-LOGICAL-c438t-1d1e505c5d6c7310aecbbc762069898f41aefdf116e0907b3c093acc81341ffb3</originalsourceid><addsrcrecordid>eNplkU1rFTEUhoMotrRd-Ack4EaFW_M1M8lGuBQ_CoVudOMmZDInbUomuSaZ0uuvN3Lr5WrP5hw4D-_5eBF6Rck5JVx-KBk2lEmhnqFjRkS3Ypyx5wf1ETor5Y606JgSVL1ER6xnXBIujtHDGts0b0w21d8DLnWZtjg5_COuA7sWOJqYWrd6G6Dgso31For_BRN2Oc148s5BhlixCcvs4zLjYkIt2KWMlwLYtDIsKUOxEC3g2VTI3oRyil64luDsMZ-g758_fbv4urq6_nJ5sb5aWcFlXdGJQkc62029HTglBuw42qFnpFdSSSeoATc5Snsgigwjt0RxY62kXFDnRn6CPu50N8s4w9S2qNkEvcl-Nnmrk_H63070t_om3WvRtR8Nsgm8fRTI6ecCperZt2NCMBHSUjQdCGuj27cb-uY_9C4tObbzNJVKDYwOfd-odzvK5lSae26_DCX6j6V6b2ljXx9uvyf_GtiA9zugtFa8gXww8onabxh7rXM</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1899721766</pqid></control><display><type>article</type><title>A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials</title><source>DOAJ Directory of Open Access Journals</source><source>Springer Nature OA Free Journals</source><source>Nature Free</source><source>EZB-FREE-00999 freely available EZB journals</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Wang, Shi-Fa ; Sun, Guang-Zhuang ; Fang, Lei-Ming ; Lei, Li ; Xiang, Xia ; Zu, Xiao-Tao</creator><creatorcontrib>Wang, Shi-Fa ; Sun, Guang-Zhuang ; Fang, Lei-Ming ; Lei, Li ; Xiang, Xia ; Zu, Xiao-Tao</creatorcontrib><description>Three ZnAl
2
O
4
samples were prepared via a modified polyacrylamide gel method using a citric acid solution with different aluminum salt starting materials, including AlCl
3
∙6H
2
O, Al
2
(SO
4
)
3
∙18H
2
O and Al(NO
3
)
3
∙9H
2
O under identical conditions. The influence of different aluminum salts on the morphologies, phase purity and optical and fluorescence properties of the as-prepared ZnAl
2
O
4
nanoparticles were studied. The experimental results demonstrate that the phase purity, particle size, morphology and optical and fluorescence properties of ZnAl
2
O
4
nanoparticles can be manipulated by the use of different aluminum salts as starting materials. The energy bandgap (Eg) values of ZnAl
2
O
4
nanoparticles increase with a decrease in particle size. The fluorescence spectra show that a major blue emission band around 400 nm and two weaker side bands located at 410 and 445 nm are observed when the excitation wavelength is 325 nm. The ZnAl
2
O
4
nanoparticles prepared from Al(NO
3
)
3
∙9H
2
O exhibit the largest emission intensity among the three ZnAl
2
O
4
samples, followed in turn by the ZnAl
2
O
4
nanoparticles prepared from Al
2
(SO
4
)
3
∙18H
2
O and AlCl
3
∙6H
2
O. These differences are attributed to combinational changes in Eg and the defect types of the ZnAl
2
O
4
nanoparticles.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep12849</identifier><identifier>PMID: 26238034</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/357/354 ; 639/624/399/354 ; 639/925/357/551 ; Aluminum ; Citric acid ; Comparative studies ; Emissions ; Fluorescence ; Humanities and Social Sciences ; multidisciplinary ; Nanoparticles ; Particle size ; Salts ; Science</subject><ispartof>Scientific reports, 2015-08, Vol.5 (1), p.12849-12849, Article 12849</ispartof><rights>The Author(s) 2015</rights><rights>Copyright Nature Publishing Group Aug 2015</rights><rights>Copyright © 2015, Macmillan Publishers Limited 2015 Macmillan Publishers Limited</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c438t-1d1e505c5d6c7310aecbbc762069898f41aefdf116e0907b3c093acc81341ffb3</citedby><cites>FETCH-LOGICAL-c438t-1d1e505c5d6c7310aecbbc762069898f41aefdf116e0907b3c093acc81341ffb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4523878/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4523878/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,864,885,27924,27925,41120,42189,51576,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26238034$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Shi-Fa</creatorcontrib><creatorcontrib>Sun, Guang-Zhuang</creatorcontrib><creatorcontrib>Fang, Lei-Ming</creatorcontrib><creatorcontrib>Lei, Li</creatorcontrib><creatorcontrib>Xiang, Xia</creatorcontrib><creatorcontrib>Zu, Xiao-Tao</creatorcontrib><title>A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Three ZnAl
2
O
4
samples were prepared via a modified polyacrylamide gel method using a citric acid solution with different aluminum salt starting materials, including AlCl
3
∙6H
2
O, Al
2
(SO
4
)
3
∙18H
2
O and Al(NO
3
)
3
∙9H
2
O under identical conditions. The influence of different aluminum salts on the morphologies, phase purity and optical and fluorescence properties of the as-prepared ZnAl
2
O
4
nanoparticles were studied. The experimental results demonstrate that the phase purity, particle size, morphology and optical and fluorescence properties of ZnAl
2
O
4
nanoparticles can be manipulated by the use of different aluminum salts as starting materials. The energy bandgap (Eg) values of ZnAl
2
O
4
nanoparticles increase with a decrease in particle size. The fluorescence spectra show that a major blue emission band around 400 nm and two weaker side bands located at 410 and 445 nm are observed when the excitation wavelength is 325 nm. The ZnAl
2
O
4
nanoparticles prepared from Al(NO
3
)
3
∙9H
2
O exhibit the largest emission intensity among the three ZnAl
2
O
4
samples, followed in turn by the ZnAl
2
O
4
nanoparticles prepared from Al
2
(SO
4
)
3
∙18H
2
O and AlCl
3
∙6H
2
O. These differences are attributed to combinational changes in Eg and the defect types of the ZnAl
2
O
4
nanoparticles.</description><subject>639/301/357/354</subject><subject>639/624/399/354</subject><subject>639/925/357/551</subject><subject>Aluminum</subject><subject>Citric acid</subject><subject>Comparative studies</subject><subject>Emissions</subject><subject>Fluorescence</subject><subject>Humanities and Social Sciences</subject><subject>multidisciplinary</subject><subject>Nanoparticles</subject><subject>Particle size</subject><subject>Salts</subject><subject>Science</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNplkU1rFTEUhoMotrRd-Ack4EaFW_M1M8lGuBQ_CoVudOMmZDInbUomuSaZ0uuvN3Lr5WrP5hw4D-_5eBF6Rck5JVx-KBk2lEmhnqFjRkS3Ypyx5wf1ETor5Y606JgSVL1ER6xnXBIujtHDGts0b0w21d8DLnWZtjg5_COuA7sWOJqYWrd6G6Dgso31For_BRN2Oc148s5BhlixCcvs4zLjYkIt2KWMlwLYtDIsKUOxEC3g2VTI3oRyil64luDsMZ-g758_fbv4urq6_nJ5sb5aWcFlXdGJQkc62029HTglBuw42qFnpFdSSSeoATc5Snsgigwjt0RxY62kXFDnRn6CPu50N8s4w9S2qNkEvcl-Nnmrk_H63070t_om3WvRtR8Nsgm8fRTI6ecCperZt2NCMBHSUjQdCGuj27cb-uY_9C4tObbzNJVKDYwOfd-odzvK5lSae26_DCX6j6V6b2ljXx9uvyf_GtiA9zugtFa8gXww8onabxh7rXM</recordid><startdate>20150804</startdate><enddate>20150804</enddate><creator>Wang, Shi-Fa</creator><creator>Sun, Guang-Zhuang</creator><creator>Fang, Lei-Ming</creator><creator>Lei, Li</creator><creator>Xiang, Xia</creator><creator>Zu, Xiao-Tao</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20150804</creationdate><title>A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials</title><author>Wang, Shi-Fa ; Sun, Guang-Zhuang ; Fang, Lei-Ming ; Lei, Li ; Xiang, Xia ; Zu, Xiao-Tao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c438t-1d1e505c5d6c7310aecbbc762069898f41aefdf116e0907b3c093acc81341ffb3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>639/301/357/354</topic><topic>639/624/399/354</topic><topic>639/925/357/551</topic><topic>Aluminum</topic><topic>Citric acid</topic><topic>Comparative studies</topic><topic>Emissions</topic><topic>Fluorescence</topic><topic>Humanities and Social Sciences</topic><topic>multidisciplinary</topic><topic>Nanoparticles</topic><topic>Particle size</topic><topic>Salts</topic><topic>Science</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Shi-Fa</creatorcontrib><creatorcontrib>Sun, Guang-Zhuang</creatorcontrib><creatorcontrib>Fang, Lei-Ming</creatorcontrib><creatorcontrib>Lei, Li</creatorcontrib><creatorcontrib>Xiang, Xia</creatorcontrib><creatorcontrib>Zu, Xiao-Tao</creatorcontrib><collection>Springer Nature OA Free Journals</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central Korea</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Shi-Fa</au><au>Sun, Guang-Zhuang</au><au>Fang, Lei-Ming</au><au>Lei, Li</au><au>Xiang, Xia</au><au>Zu, Xiao-Tao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><addtitle>Sci Rep</addtitle><date>2015-08-04</date><risdate>2015</risdate><volume>5</volume><issue>1</issue><spage>12849</spage><epage>12849</epage><pages>12849-12849</pages><artnum>12849</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Three ZnAl
2
O
4
samples were prepared via a modified polyacrylamide gel method using a citric acid solution with different aluminum salt starting materials, including AlCl
3
∙6H
2
O, Al
2
(SO
4
)
3
∙18H
2
O and Al(NO
3
)
3
∙9H
2
O under identical conditions. The influence of different aluminum salts on the morphologies, phase purity and optical and fluorescence properties of the as-prepared ZnAl
2
O
4
nanoparticles were studied. The experimental results demonstrate that the phase purity, particle size, morphology and optical and fluorescence properties of ZnAl
2
O
4
nanoparticles can be manipulated by the use of different aluminum salts as starting materials. The energy bandgap (Eg) values of ZnAl
2
O
4
nanoparticles increase with a decrease in particle size. The fluorescence spectra show that a major blue emission band around 400 nm and two weaker side bands located at 410 and 445 nm are observed when the excitation wavelength is 325 nm. The ZnAl
2
O
4
nanoparticles prepared from Al(NO
3
)
3
∙9H
2
O exhibit the largest emission intensity among the three ZnAl
2
O
4
samples, followed in turn by the ZnAl
2
O
4
nanoparticles prepared from Al
2
(SO
4
)
3
∙18H
2
O and AlCl
3
∙6H
2
O. These differences are attributed to combinational changes in Eg and the defect types of the ZnAl
2
O
4
nanoparticles.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>26238034</pmid><doi>10.1038/srep12849</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4523878 |
| source | DOAJ Directory of Open Access Journals; Springer Nature OA Free Journals; Nature Free; EZB-FREE-00999 freely available EZB journals; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | 639/301/357/354 639/624/399/354 639/925/357/551 Aluminum Citric acid Comparative studies Emissions Fluorescence Humanities and Social Sciences multidisciplinary Nanoparticles Particle size Salts Science |
| title | A comparative study of ZnAl2O4 nanoparticles synthesized from different aluminum salts for use as fluorescence materials |
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