A Polymer Lithium-Oxygen Battery
Herein we report the characteristics of a lithium-oxygen battery using a solid polymer membrane as the electrolyte separator. The polymer electrolyte, fully characterized in terms of electrochemical properties, shows suitable conductivity at room temperature allowing the reversible cycling of the Li...
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| Veröffentlicht in: | Scientific reports 2015-08, Vol.5 (1), p.12307-12307, Article 12307 |
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| creator | Elia, Giuseppe Antonio Hassoun, Jusef |
| description | Herein we report the characteristics of a lithium-oxygen battery using a solid polymer membrane as the electrolyte separator. The polymer electrolyte, fully characterized in terms of electrochemical properties, shows suitable conductivity at room temperature allowing the reversible cycling of the Li-O
2
battery with a specific capacity as high as 25,000 mAh g
C
−1
reflected in a surface capacity of 12.5 mAh cm
−2
. The electrochemical formation and dissolution of the lithium peroxide during Li-O
2
polymer cell operation is investigated by electrochemical techniques combined with X-ray diffraction study, demonstrating the process reversibility. The excellent cell performances in terms of delivered capacity, in addition to its solid configuration allowing the safe use of lithium metal as high capacity anode, demonstrate the suitability of the polymer lithium-oxygen as high-energy storage system. |
| doi_str_mv | 10.1038/srep12307 |
| format | Article |
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2
battery with a specific capacity as high as 25,000 mAh g
C
−1
reflected in a surface capacity of 12.5 mAh cm
−2
. The electrochemical formation and dissolution of the lithium peroxide during Li-O
2
polymer cell operation is investigated by electrochemical techniques combined with X-ray diffraction study, demonstrating the process reversibility. The excellent cell performances in terms of delivered capacity, in addition to its solid configuration allowing the safe use of lithium metal as high capacity anode, demonstrate the suitability of the polymer lithium-oxygen as high-energy storage system.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/srep12307</identifier><identifier>PMID: 26238552</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/299 ; 639/638/161/891 ; Dissolution ; Electrochemistry ; Electrolytes ; Energy storage ; Humanities and Social Sciences ; Lithium ; multidisciplinary ; Oxygen ; Peroxide ; Polymers ; Science ; Specific capacity ; Temperature effects ; X-ray diffraction</subject><ispartof>Scientific reports, 2015-08, Vol.5 (1), p.12307-12307, Article 12307</ispartof><rights>The Author(s) 2015</rights><rights>Copyright Nature Publishing Group Aug 2015</rights><rights>Copyright © 2015, Macmillan Publishers Limited 2015 Macmillan Publishers Limited</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c504t-66aca46c18d17ed8763d9ef6903df711753e64b7c462bd7cb6d02d0e7b73a6d63</citedby><cites>FETCH-LOGICAL-c504t-66aca46c18d17ed8763d9ef6903df711753e64b7c462bd7cb6d02d0e7b73a6d63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4523859/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4523859/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,860,881,27901,27902,41096,42165,51551,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26238552$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Elia, Giuseppe Antonio</creatorcontrib><creatorcontrib>Hassoun, Jusef</creatorcontrib><title>A Polymer Lithium-Oxygen Battery</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><addtitle>Sci Rep</addtitle><description>Herein we report the characteristics of a lithium-oxygen battery using a solid polymer membrane as the electrolyte separator. The polymer electrolyte, fully characterized in terms of electrochemical properties, shows suitable conductivity at room temperature allowing the reversible cycling of the Li-O
2
battery with a specific capacity as high as 25,000 mAh g
C
−1
reflected in a surface capacity of 12.5 mAh cm
−2
. The electrochemical formation and dissolution of the lithium peroxide during Li-O
2
polymer cell operation is investigated by electrochemical techniques combined with X-ray diffraction study, demonstrating the process reversibility. 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The polymer electrolyte, fully characterized in terms of electrochemical properties, shows suitable conductivity at room temperature allowing the reversible cycling of the Li-O
2
battery with a specific capacity as high as 25,000 mAh g
C
−1
reflected in a surface capacity of 12.5 mAh cm
−2
. The electrochemical formation and dissolution of the lithium peroxide during Li-O
2
polymer cell operation is investigated by electrochemical techniques combined with X-ray diffraction study, demonstrating the process reversibility. The excellent cell performances in terms of delivered capacity, in addition to its solid configuration allowing the safe use of lithium metal as high capacity anode, demonstrate the suitability of the polymer lithium-oxygen as high-energy storage system.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>26238552</pmid><doi>10.1038/srep12307</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | 639/301/299 639/638/161/891 Dissolution Electrochemistry Electrolytes Energy storage Humanities and Social Sciences Lithium multidisciplinary Oxygen Peroxide Polymers Science Specific capacity Temperature effects X-ray diffraction |
| title | A Polymer Lithium-Oxygen Battery |
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