Mechanisms and Free Energies of Enzymatic Reactions

Experiments and computational results based on Wolfenden's theories provide abundant evidence that the very large observated reductions of the free energy activation can be achieved through strong synergism of enzyme and substrate interactions although in other cases enzyme catalysis may involv...

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Veröffentlicht in:	Chemical reviews 2006-08, Vol.106 (8), p.3188-3209
Hauptverfasser:	Gao, Jiali, Ma, Shuhua, Major, Dan T, Nam, Kwangho, Pu, Jingzhi, Truhlar, Donald G
Format:	Artikel
Sprache:	eng
Schlagworte:	Biochemistry Biophysics Catalysis Chemical reactions Computer Simulation Enzymes Enzymes - chemistry Hydrogen Bonding Models, Chemical Molecular Conformation Quantum Theory Solutions - chemistry Theory Thermodynamics Water - chemistry
Online-Zugang:	Volltext
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