Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species

Acting as a bridge between the heterogeneous and homogeneous realms, the use of discrete, well-defined, solid-state organometallic complexes for synthesis and catalysis is a remarkably undeveloped field. Here, we present a review of this topic, focusing on describing the key transformations that can...

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Veröffentlicht in:	Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 2015-03, Vol.373 (2037), p.20140187
Hauptverfasser:	Pike, Sebastian D., Weller, Andrew S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Organometallic Reactivity Review Solid State
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container_title	Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences
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description	Acting as a bridge between the heterogeneous and homogeneous realms, the use of discrete, well-defined, solid-state organometallic complexes for synthesis and catalysis is a remarkably undeveloped field. Here, we present a review of this topic, focusing on describing the key transformations that can be observed at a transition-metal centre, as well as the use of well-defined organometallic complexes in the solid state as catalysts. There is a particular focus upon gas-solid reactivity/catalysis and single-crystal-to-single-crystal transformations.
doi_str_mv	10.1098/rsta.2014.0187
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subjects	Catalysis Organometallic Reactivity Review Solid State
title	Organometallic synthesis, reactivity and catalysis in the solid state using well-defined single-site species
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