Sprayable Elastic Conductors Based on Block Copolymer Silver Nanoparticle Composites
Block copolymer silver nanoparticle composite elastic conductors were fabricated through solution blow spinning and subsequent nanoparticle nucleation. The reported technique allows for conformal deposition onto nonplanar substrates. We additionally demonstrated the ability to tune the strain depend...
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| Veröffentlicht in: | ACS nano 2015-01, Vol.9 (1), p.336-344 |
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| creator | Vural, Mert Behrens, Adam M Ayyub, Omar B Ayoub, Joseph J Kofinas, Peter |
| description | Block copolymer silver nanoparticle composite elastic conductors were fabricated through solution blow spinning and subsequent nanoparticle nucleation. The reported technique allows for conformal deposition onto nonplanar substrates. We additionally demonstrated the ability to tune the strain dependence of the electrical properties by adjusting nanoparticle precursor concentration or localized nanoparticle nucleation. The stretchable fiber mats were able to display electrical conductivity values as high as 2000 ± 200 S/cm with only a 12% increase in resistance after 400 cycles of 150% strain. Stretchable elastic conductors with similar and higher bulk conductivity have not achieved comparable stability of electrical properties. These unique electromechanical characteristics are primarily the result of structural changes during mechanical deformation. The versatility of this approach was demonstrated by constructing a stretchable light emitting diode circuit and a strain sensor on planar and nonplanar substrates. |
| doi_str_mv | 10.1021/nn505306h |
| format | Article |
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The reported technique allows for conformal deposition onto nonplanar substrates. We additionally demonstrated the ability to tune the strain dependence of the electrical properties by adjusting nanoparticle precursor concentration or localized nanoparticle nucleation. The stretchable fiber mats were able to display electrical conductivity values as high as 2000 ± 200 S/cm with only a 12% increase in resistance after 400 cycles of 150% strain. Stretchable elastic conductors with similar and higher bulk conductivity have not achieved comparable stability of electrical properties. These unique electromechanical characteristics are primarily the result of structural changes during mechanical deformation. The versatility of this approach was demonstrated by constructing a stretchable light emitting diode circuit and a strain sensor on planar and nonplanar substrates.</description><subject>Block copolymers</subject><subject>Butadienes - chemistry</subject><subject>Conductors</subject><subject>Elasticity</subject><subject>Electric Conductivity</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Nanocomposites - chemistry</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Nucleation</subject><subject>Pentanes - chemistry</subject><subject>Polystyrenes - chemistry</subject><subject>Resistivity</subject><subject>Silver</subject><subject>Silver - chemistry</subject><subject>Spinning</subject><subject>Strain</subject><subject>Stress, Mechanical</subject><issn>1936-0851</issn><issn>1936-086X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>N~.</sourceid><sourceid>EIF</sourceid><recordid>eNptkU9LJDEQxcOy4ujoYb-A9GVhPYxb6XSS7ouwDv6DwT2o4C1UpzNrj-mkTbqF-fZGxh0UPL2C96tXRRUhPyicUMjpb-c4cAbi8RvZoxUTMyjFw_dtzemE7Me4AuCylGKXTHJeVJSD3CN3t33ANdbWZOcW49DqbO5dM-rBh5idYTRN5l12Zr1-Sk7v7bozIbtt7UuSG3S-x5C6Uv_cd72P7WDiAdlZoo3m8F2n5P7i_G5-NVv8vbye_1nMkEMxzLQUkla1NLRgTOBSsrrOS6RlnoNhmi2FLHmDBTLJywaqspIcoGkYVFpWec2m5HST2491Zxpt3BDQqj60HYa18tiqz45rH9U__6IKRkEwmQJ-vQcE_zyaOKiujdpYi874MSoqRQ6cc1Ym9HiD6uBjDGa5HUNBvX1Bbb-Q2KOPe23J_2dPwM8NgDqqlR-DS2f6IugVTi-PJg</recordid><startdate>20150127</startdate><enddate>20150127</enddate><creator>Vural, Mert</creator><creator>Behrens, Adam M</creator><creator>Ayyub, Omar B</creator><creator>Ayoub, Joseph J</creator><creator>Kofinas, Peter</creator><general>American Chemical Society</general><scope>N~.</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>5PM</scope></search><sort><creationdate>20150127</creationdate><title>Sprayable Elastic Conductors Based on Block Copolymer Silver Nanoparticle Composites</title><author>Vural, Mert ; 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The reported technique allows for conformal deposition onto nonplanar substrates. We additionally demonstrated the ability to tune the strain dependence of the electrical properties by adjusting nanoparticle precursor concentration or localized nanoparticle nucleation. The stretchable fiber mats were able to display electrical conductivity values as high as 2000 ± 200 S/cm with only a 12% increase in resistance after 400 cycles of 150% strain. Stretchable elastic conductors with similar and higher bulk conductivity have not achieved comparable stability of electrical properties. These unique electromechanical characteristics are primarily the result of structural changes during mechanical deformation. The versatility of this approach was demonstrated by constructing a stretchable light emitting diode circuit and a strain sensor on planar and nonplanar substrates.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>25491507</pmid><doi>10.1021/nn505306h</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Block copolymers Butadienes - chemistry Conductors Elasticity Electric Conductivity Metal Nanoparticles - chemistry Nanocomposites - chemistry Nanostructure Nanotechnology Nucleation Pentanes - chemistry Polystyrenes - chemistry Resistivity Silver Silver - chemistry Spinning Strain Stress, Mechanical |
| title | Sprayable Elastic Conductors Based on Block Copolymer Silver Nanoparticle Composites |
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