Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks
Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible add...
Gespeichert in:
| Veröffentlicht in: | International journal of molecular sciences 2015-01, Vol.16 (1), p.990-1007 |
|---|---|
| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 1007 |
|---|---|
| container_issue | 1 |
| container_start_page | 990 |
| container_title | International journal of molecular sciences |
| container_volume | 16 |
| creator | Brassinne, Jérémy Jochum, Florian D Fustin, Charles-André Gohy, Jean-François |
| description | Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks. |
| doi_str_mv | 10.3390/ijms16010990 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4307286</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3579136951</sourcerecordid><originalsourceid>FETCH-LOGICAL-c412t-aec330f3ccd8764586b0e189c824898a69d36071b04b6a9e9f63f4419a79d8ef3</originalsourceid><addsrcrecordid>eNpdkc9LHTEQx0OxVKu99VwWvHjo6uTHZpOLIA9tC4IgepSQl5315XU32Sa7lte_3hWtPD3NwHzmy3fmS8hXCsecazjx6z5TCRS0hg9kjwrGSgBZ72z1u-RzzmsAxlmlP5FdVlVSg2J75O4aH9B2PtwX4wqLPA3J9rFDN3U2FcGOU8IitkX2DZZuZX0oRkzDJvnGByzbKbjRxzAr_MOmGGK36XHew_FvTL_zAfnY2i7jl5e6T24vzm8WP8vLqx-_FmeXpROUjaVFxzm03LlG1VJUSi4BqdJOMaG0slI3XEJNlyCW0mrUreStEFTbWjcKW75PTp91h2nZY-MwjMl2Zki-t2ljovXm7ST4lbmPD0ZwqJmSs8DRi0CKfybMo-l9dth1NmCcsqGzq7rmQugZPXyHruOU5g88URWlmlYAM_X9mXIp5pywfTVDwTzlZrZzm_Fv2we8wv-D4o_teJYY</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1651191500</pqid></control><display><type>article</type><title>Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks</title><source>PubMed (Medline)</source><source>MDPI - Multidisciplinary Digital Publishing Institute</source><source>MEDLINE</source><source>Free E-Journal (出版社公開部分のみ）</source><creator>Brassinne, Jérémy ; Jochum, Florian D ; Fustin, Charles-André ; Gohy, Jean-François</creator><creatorcontrib>Brassinne, Jérémy ; Jochum, Florian D ; Fustin, Charles-André ; Gohy, Jean-François</creatorcontrib><description>Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks.</description><identifier>ISSN: 1422-0067</identifier><identifier>ISSN: 1661-6596</identifier><identifier>EISSN: 1422-0067</identifier><identifier>DOI: 10.3390/ijms16010990</identifier><identifier>PMID: 25569082</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Cobalt - chemistry ; Hydrogels ; Hydrogels - chemistry ; Magnetic Resonance Spectroscopy ; Mechanical properties ; Methacrylates - chemical synthesis ; Methacrylates - chemistry ; Nylons - chemical synthesis ; Nylons - chemistry ; Polymerization ; Polymers ; Pyridines - chemistry ; Rheology</subject><ispartof>International journal of molecular sciences, 2015-01, Vol.16 (1), p.990-1007</ispartof><rights>Copyright MDPI AG 2015</rights><rights>2015 by the authors; licensee MDPI, Basel, Switzerland. 2015</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c412t-aec330f3ccd8764586b0e189c824898a69d36071b04b6a9e9f63f4419a79d8ef3</citedby><cites>FETCH-LOGICAL-c412t-aec330f3ccd8764586b0e189c824898a69d36071b04b6a9e9f63f4419a79d8ef3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4307286/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4307286/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27901,27902,53766,53768</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25569082$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Brassinne, Jérémy</creatorcontrib><creatorcontrib>Jochum, Florian D</creatorcontrib><creatorcontrib>Fustin, Charles-André</creatorcontrib><creatorcontrib>Gohy, Jean-François</creatorcontrib><title>Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks</title><title>International journal of molecular sciences</title><addtitle>Int J Mol Sci</addtitle><description>Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks.</description><subject>Cobalt - chemistry</subject><subject>Hydrogels</subject><subject>Hydrogels - chemistry</subject><subject>Magnetic Resonance Spectroscopy</subject><subject>Mechanical properties</subject><subject>Methacrylates - chemical synthesis</subject><subject>Methacrylates - chemistry</subject><subject>Nylons - chemical synthesis</subject><subject>Nylons - chemistry</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Pyridines - chemistry</subject><subject>Rheology</subject><issn>1422-0067</issn><issn>1661-6596</issn><issn>1422-0067</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>8G5</sourceid><sourceid>BENPR</sourceid><sourceid>GUQSH</sourceid><sourceid>M2O</sourceid><recordid>eNpdkc9LHTEQx0OxVKu99VwWvHjo6uTHZpOLIA9tC4IgepSQl5315XU32Sa7lte_3hWtPD3NwHzmy3fmS8hXCsecazjx6z5TCRS0hg9kjwrGSgBZ72z1u-RzzmsAxlmlP5FdVlVSg2J75O4aH9B2PtwX4wqLPA3J9rFDN3U2FcGOU8IitkX2DZZuZX0oRkzDJvnGByzbKbjRxzAr_MOmGGK36XHew_FvTL_zAfnY2i7jl5e6T24vzm8WP8vLqx-_FmeXpROUjaVFxzm03LlG1VJUSi4BqdJOMaG0slI3XEJNlyCW0mrUreStEFTbWjcKW75PTp91h2nZY-MwjMl2Zki-t2ljovXm7ST4lbmPD0ZwqJmSs8DRi0CKfybMo-l9dth1NmCcsqGzq7rmQugZPXyHruOU5g88URWlmlYAM_X9mXIp5pywfTVDwTzlZrZzm_Fv2we8wv-D4o_teJYY</recordid><startdate>20150105</startdate><enddate>20150105</enddate><creator>Brassinne, Jérémy</creator><creator>Jochum, Florian D</creator><creator>Fustin, Charles-André</creator><creator>Gohy, Jean-François</creator><general>MDPI AG</general><general>MDPI</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88E</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>K9.</scope><scope>M0S</scope><scope>M1P</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20150105</creationdate><title>Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks</title><author>Brassinne, Jérémy ; Jochum, Florian D ; Fustin, Charles-André ; Gohy, Jean-François</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c412t-aec330f3ccd8764586b0e189c824898a69d36071b04b6a9e9f63f4419a79d8ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Cobalt - chemistry</topic><topic>Hydrogels</topic><topic>Hydrogels - chemistry</topic><topic>Magnetic Resonance Spectroscopy</topic><topic>Mechanical properties</topic><topic>Methacrylates - chemical synthesis</topic><topic>Methacrylates - chemistry</topic><topic>Nylons - chemical synthesis</topic><topic>Nylons - chemistry</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Pyridines - chemistry</topic><topic>Rheology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Brassinne, Jérémy</creatorcontrib><creatorcontrib>Jochum, Florian D</creatorcontrib><creatorcontrib>Fustin, Charles-André</creatorcontrib><creatorcontrib>Gohy, Jean-François</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Proquest Health & Medical Complete</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>ProQuest research library</collection><collection>Research Library (Corporate)</collection><collection>Publicly Available Content (ProQuest)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>International journal of molecular sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Brassinne, Jérémy</au><au>Jochum, Florian D</au><au>Fustin, Charles-André</au><au>Gohy, Jean-François</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks</atitle><jtitle>International journal of molecular sciences</jtitle><addtitle>Int J Mol Sci</addtitle><date>2015-01-05</date><risdate>2015</risdate><volume>16</volume><issue>1</issue><spage>990</spage><epage>1007</epage><pages>990-1007</pages><issn>1422-0067</issn><issn>1661-6596</issn><eissn>1422-0067</eissn><abstract>Nowadays, finely controlling the mechanical properties of polymeric materials is possible by incorporating supramolecular motifs into their architecture. In this context, the synthesis of a side-chain terpyridine-functionalized poly(2-(dimethylamino)ethyl methacrylate) is reported via reversible addition-fragmentation chain transfer polymerization. By addition of transition metal ions, concentrated aqueous solutions of this polymer turn into metallo-supramolecular hydrogels whose dynamic mechanical properties are investigated by rotational rheometry. Hence, the possibility for the material to relax mechanical constrains via dissociation of transient cross-links is brought into light. In addition, the complex phenomena occurring under large oscillatory shear are interpreted in the context of transient networks.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>25569082</pmid><doi>10.3390/ijms16010990</doi><tpages>18</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1422-0067 |
| ispartof | International journal of molecular sciences, 2015-01, Vol.16 (1), p.990-1007 |
| issn | 1422-0067 1661-6596 1422-0067 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4307286 |
| source | PubMed (Medline); MDPI - Multidisciplinary Digital Publishing Institute; MEDLINE; Free E-Journal (出版社公開部分のみ） |
| subjects | Cobalt - chemistry Hydrogels Hydrogels - chemistry Magnetic Resonance Spectroscopy Mechanical properties Methacrylates - chemical synthesis Methacrylates - chemistry Nylons - chemical synthesis Nylons - chemistry Polymerization Polymers Pyridines - chemistry Rheology |
| title | Revealing the supramolecular nature of side-chain terpyridine-functionalized polymer networks |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-29T07%3A33%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Revealing%20the%20supramolecular%20nature%20of%20side-chain%20terpyridine-functionalized%20polymer%20networks&rft.jtitle=International%20journal%20of%20molecular%20sciences&rft.au=Brassinne,%20J%C3%A9r%C3%A9my&rft.date=2015-01-05&rft.volume=16&rft.issue=1&rft.spage=990&rft.epage=1007&rft.pages=990-1007&rft.issn=1422-0067&rft.eissn=1422-0067&rft_id=info:doi/10.3390/ijms16010990&rft_dat=%3Cproquest_pubme%3E3579136951%3C/proquest_pubme%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1651191500&rft_id=info:pmid/25569082&rfr_iscdi=true |