Evaluation of the three-phase equilibrium method for measuring temperature dependence of internally consistent partition coefficients (KOW, KOA, and KAW) for volatile methylsiloxanes and trimethylsilanol

Partitioning equilibria and their temperature dependence of chemicals between different environmental media are important in determining the fate, transport, and distribution of contaminants. Unfortunately, internally consistent air/water (KAW), 1‐octanol/air (KOA), and 1‐octanol/water (KOW) partiti...

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Veröffentlicht in:	Environmental toxicology and chemistry 2014-12, Vol.33 (12), p.2702-2710
Hauptverfasser:	Xu, Shihe, Kropscott, Bruce
Format:	Artikel
Sprache:	eng
Schlagworte:	air Alcohols Alkanes Analytical chemistry Applied sciences Benzoates Benzoic acid Chemical partition Chemical reactions Coefficients Contaminants ecotoxicology Enthalpy Enthalpy and entropy changes Enthalpy and entropy compensation effects Entropy Environmental Chemistry Exact sciences and technology Global environmental pollution Octanol Organic chemicals Organic chemistry Organosilicon compounds Partition coefficients Partitioning Partitions perfluorocarbons Phase equilibrium method Phenolic compounds Phenols Pollution Solvents Sulfonamides Temperature Temperature dependence Temperature effects Temperature measurement Toxicology Volatile methylsiloxanes
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