Crystal structure of bis(acetato-κO)diaqua(2,2′-bipyridine-κ2 N,N′)manganese(II)
In the title monomeric manganese(II) complex, [Mn(CH 3 COO) 2 (C 10 H 8 N 2 )(H 2 O) 2 ], the metal ion is coordinated by a bidentate 2,2′-bipyridine (bpy) ligand, two water molecules and two axial acetate anions, resulting in a highly distorted octahedral environment. The aqua ligands are stabil...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-08, Vol.70 (Pt 9), p.m326-m327 |
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| container_issue | Pt 9 |
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| container_title | Acta crystallographica. Section E, Structure reports online |
| container_volume | 70 |
| creator | Saravanan, Natarajan Selvam, Parasuraman |
| description | In the title monomeric manganese(II) complex, [Mn(CH
3
COO)
2
(C
10
H
8
N
2
)(H
2
O)
2
], the metal ion is coordinated by a bidentate 2,2′-bipyridine (bpy) ligand, two water molecules and two axial acetate anions, resulting in a highly distorted octahedral environment. The aqua ligands are stabilized by the formation of strong intramolecular hydrogen bonds with the uncoordinated acetate O atoms, giving rise to pseudo-bridging arrangement of the terminal acetate groups. In the crystal, the molecules form [010] zigzag chains
via
O—H⋯O hydrogen bonds involving the aqua ligands and acetate O atoms. Further, the water and bpy ligands are
trans
to each other, and are arranged in an off-set fashion showing intermolecular π–π stacking between nearly parallel bipy rings, the centroid–centroid separations being 3.8147 (12) and 3.9305 (13) Å. |
| doi_str_mv | 10.1107/S1600536814017814 |
| format | Article |
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3
COO)
2
(C
10
H
8
N
2
)(H
2
O)
2
], the metal ion is coordinated by a bidentate 2,2′-bipyridine (bpy) ligand, two water molecules and two axial acetate anions, resulting in a highly distorted octahedral environment. The aqua ligands are stabilized by the formation of strong intramolecular hydrogen bonds with the uncoordinated acetate O atoms, giving rise to pseudo-bridging arrangement of the terminal acetate groups. In the crystal, the molecules form [010] zigzag chains
via
O—H⋯O hydrogen bonds involving the aqua ligands and acetate O atoms. Further, the water and bpy ligands are
trans
to each other, and are arranged in an off-set fashion showing intermolecular π–π stacking between nearly parallel bipy rings, the centroid–centroid separations being 3.8147 (12) and 3.9305 (13) Å.</description><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536814017814</identifier><identifier>PMID: 25309183</identifier><language>eng</language><publisher>International Union of Crystallography</publisher><subject>Data Reports</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2014-08, Vol.70 (Pt 9), p.m326-m327</ispartof><rights>Saravanan and Selvam 2014 2014</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186102/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC4186102/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,725,778,782,862,883,27911,27912,53778,53780</link.rule.ids></links><search><creatorcontrib>Saravanan, Natarajan</creatorcontrib><creatorcontrib>Selvam, Parasuraman</creatorcontrib><title>Crystal structure of bis(acetato-κO)diaqua(2,2′-bipyridine-κ2 N,N′)manganese(II)</title><title>Acta crystallographica. Section E, Structure reports online</title><description>In the title monomeric manganese(II) complex, [Mn(CH
3
COO)
2
(C
10
H
8
N
2
)(H
2
O)
2
], the metal ion is coordinated by a bidentate 2,2′-bipyridine (bpy) ligand, two water molecules and two axial acetate anions, resulting in a highly distorted octahedral environment. The aqua ligands are stabilized by the formation of strong intramolecular hydrogen bonds with the uncoordinated acetate O atoms, giving rise to pseudo-bridging arrangement of the terminal acetate groups. In the crystal, the molecules form [010] zigzag chains
via
O—H⋯O hydrogen bonds involving the aqua ligands and acetate O atoms. Further, the water and bpy ligands are
trans
to each other, and are arranged in an off-set fashion showing intermolecular π–π stacking between nearly parallel bipy rings, the centroid–centroid separations being 3.8147 (12) and 3.9305 (13) Å.</description><subject>Data Reports</subject><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpjYJA0NNAzNDQw1w82NDMwMDU2szA0MTA0B5JMDJwgIV2QGAcDV3FxloGBoZm5kSE7A4eRqbGBpaGFMSdDnHNRZXFJYo5CcUlRaXJJaVGqQn6aQlJm8aG1GonJqSWJJfm653b5a6ZkHlqbWFiaCBQ20jF61LBJNwkoUlBZlJmSmZcKVGKk4KfjBxTXzE3MS0_MSy1O1fD01ORhYE1LzClO5YXS3Ax2bq4hzh66BaVJuakpyal5JUWJOfEFRZm5iUWV8fmJmfGoMnmZGfHp-WXxJoYWZoYGRsYUGwAAtCZmEg</recordid><startdate>20140813</startdate><enddate>20140813</enddate><creator>Saravanan, Natarajan</creator><creator>Selvam, Parasuraman</creator><general>International Union of Crystallography</general><scope>5PM</scope></search><sort><creationdate>20140813</creationdate><title>Crystal structure of bis(acetato-κO)diaqua(2,2′-bipyridine-κ2 N,N′)manganese(II)</title><author>Saravanan, Natarajan ; Selvam, Parasuraman</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-pubmedcentral_primary_oai_pubmedcentral_nih_gov_41861023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Data Reports</topic><toplevel>online_resources</toplevel><creatorcontrib>Saravanan, Natarajan</creatorcontrib><creatorcontrib>Selvam, Parasuraman</creatorcontrib><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saravanan, Natarajan</au><au>Selvam, Parasuraman</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Crystal structure of bis(acetato-κO)diaqua(2,2′-bipyridine-κ2 N,N′)manganese(II)</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><date>2014-08-13</date><risdate>2014</risdate><volume>70</volume><issue>Pt 9</issue><spage>m326</spage><epage>m327</epage><pages>m326-m327</pages><eissn>1600-5368</eissn><abstract>In the title monomeric manganese(II) complex, [Mn(CH
3
COO)
2
(C
10
H
8
N
2
)(H
2
O)
2
], the metal ion is coordinated by a bidentate 2,2′-bipyridine (bpy) ligand, two water molecules and two axial acetate anions, resulting in a highly distorted octahedral environment. The aqua ligands are stabilized by the formation of strong intramolecular hydrogen bonds with the uncoordinated acetate O atoms, giving rise to pseudo-bridging arrangement of the terminal acetate groups. In the crystal, the molecules form [010] zigzag chains
via
O—H⋯O hydrogen bonds involving the aqua ligands and acetate O atoms. Further, the water and bpy ligands are
trans
to each other, and are arranged in an off-set fashion showing intermolecular π–π stacking between nearly parallel bipy rings, the centroid–centroid separations being 3.8147 (12) and 3.9305 (13) Å.</abstract><pub>International Union of Crystallography</pub><pmid>25309183</pmid><doi>10.1107/S1600536814017814</doi><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | EISSN: 1600-5368 |
| ispartof | Acta crystallographica. Section E, Structure reports online, 2014-08, Vol.70 (Pt 9), p.m326-m327 |
| issn | 1600-5368 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4186102 |
| source | DOAJ Directory of Open Access Journals; PubMed Central Open Access; PubMed Central; Free Full-Text Journals in Chemistry |
| subjects | Data Reports |
| title | Crystal structure of bis(acetato-κO)diaqua(2,2′-bipyridine-κ2 N,N′)manganese(II) |
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