The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

All‐carbon quaternary stereocenters have posed significant challenges in the synthesis of complex natural products. These important structural motifs have inspired the development of broadly applicable palladium‐catalyzed asymmetric allylic alkylation reactions of unstabilized non‐biased enolates fo...

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Veröffentlicht in:	European journal of organic chemistry 2013-05, Vol.2013 (14), p.2745-2759
Hauptverfasser:	Hong, Allen Y., Stoltz, Brian M.
Format:	Artikel
Sprache:	eng
Schlagworte:	All-carbon quaternary stereocenters Allylation Asymmetric cataly­sis Carbon Natural products Palladium Total synthesis
Online-Zugang:	Volltext
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