Ionic liquid electrolytes for Li-air batteries: lithium metal cycling
In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (Pyr14TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance s...
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| Veröffentlicht in: | International journal of molecular sciences 2014-05, Vol.15 (5), p.8122-8137 |
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| container_title | International journal of molecular sciences |
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| creator | Grande, Lorenzo Paillard, Elie Kim, Guk-Tae Monaco, Simone Passerini, Stefano |
| description | In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (Pyr14TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance spectroscopy measurements and galvanostatic cycling at different temperatures are performed to analyze the influence of temperature on the stabilization of the solid electrolyte interphase (SEI), showing that TFSI-based ionic liquids (ILs) rank among the best candidates for long-lasting Li-air cells. |
| doi_str_mv | 10.3390/ijms15058122 |
| format | Article |
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| source | MEDLINE; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; MDPI - Multidisciplinary Digital Publishing Institute; PubMed Central |
| subjects | Batteries Electric Power Supplies Electrodes Electrolytes Electrolytes - chemistry Hydrocarbons, Fluorinated - chemistry Imides - chemistry Ionic Liquids - chemistry Lithium Lithium - chemistry Pyrrolidines - chemistry |
| title | Ionic liquid electrolytes for Li-air batteries: lithium metal cycling |
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